After the advent of the quartz crystal microbalance (QCM) technology, various QCM-based sensing systems have got certain applications in many science and technology fields and resulted in dramatic progress in these fields. The core advantage of QCM is its high mass sensitivity which leads to high accuracy and low detection limit. For a QCM, the mass sensitivity is determined by the diameter and thickness of the electrode to a certain extent when the frequency of the quartz wafer is already determined. Theoretical approximate calculation reveals that there is an optimum electrode diameter corresponding to the maximum sensitivity. This is different from the traditional opinion that the smaller the electrode, the higher the mass sensitivity. A plating experiment was carried out using 28 QCMs with different electrode diameters, and the experimental results verified the existence of the optimum diameter. This study is helpful to obtain higher mass sensitivity by optimizing electrode parameters.
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