The ICP in closed quartz chamber is an effective solution to local stealth of aircraft. The attenuation of the electromagnetic wave is strongly affected by distribution of electron density in incidence direction. In this paper, an experiment that the planar ICP discharged in all-quartz chamber (30.8 cm×30.8 cm×5.8 cm) was conducted. The E-H mode transition of Ar/Air ICP was observed, and the width and the proportion of ICP area versus the RF power were measured. Such physical phenomena were explained rationally by ICP-source theoretical model. A new microwave diagnostics is presented based on the Hβ spectrum broadening and the characteristics of planar-coil ICP. It is used to diagnose the spatial electron density distribution of Ar/Air in incidence direction. The parameters of electron density distribution function in the incident direction are separately solved by the fitting results of the Hβ stack broadening and microwave interferometer. And the curves of electron density distribution versus RF power are obtained. We obtain a stable ring plasma source with electron density varying from 0.5×1011~3.2×1011 cm-3. The experiment demonstrates that electron density is prominently affected by the RF power and gas species. The peak value of electron density is positioned near the center of ICP. It is shown that the electron density of Ar ICP is higher than the air, but the area of air ICP is larger through comparing the curves of Ar/Air electron density.
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Adv Sci (Weinh)
December 2024
Institute of Materials Science, Technische Universität Darmstadt, Peter-Grünberg-Str. 2, D-64287, Darmstadt, Germany.
The design of cathode/electrolyte interfaces in high-energy density Li-ion batteries is critical to protect the surface against undesirable oxygen release from the cathodes when batteries are charged to high voltage. However, the involvement of the engineered interface in the cationic and anionic redox reactions associated with (de-)lithiation is often ignored, mostly due to the difficulty to separate these processes from chemical/catalytic reactions at the cathode/electrolyte interface. Here, a new electron energy band diagrams concept is developed that includes the examination of the electrochemical- and ionization- potentials evolution upon batteries cycling.
View Article and Find Full Text PDFSci Rep
December 2024
Department of Physics, University of Liverpool, Oxford Street, Liverpool, L69 7ZE, UK.
Topological semimetals have recently garnered widespread interest in the quantum materials research community due to their symmetry-protected surface states with dissipationless transport which have potential applications in next-generation low-power electronic devices. One such material, [Formula: see text], exhibits Dirac nodal arcs and although the topological properties of single crystals have been investigated, there have been no reports in crystalline thin film geometry. We examined the growth of [Formula: see text] heterostructures on a range of single crystals by optimizing the electron beam evaporation of Pt and Sn and studied the effect of vacuum thermal annealing on phase and crystallinity.
View Article and Find Full Text PDFEcotoxicol Environ Saf
December 2024
Hebei University of Science and Technology, 050018, China. Electronic address:
Polylactic acid (PLA) composites with high straw content face several challenges, primarily due to the inherent brittleness of straw and its poor compatibility with the polymer matrix. In this study, scanning electron microscopy (SEM) was used to analyze the microscopic structure of wheat straw chemically modified by NaOH and the silane coupling agent, and it was concluded that both treatments effectively removed waxes and silica from the surface of the straw, enhanced fiber roughness, and improved interfacial adhesion. Notably, the silane coupling agent treatment not only facilitated the formation of chemical bonds between the straw fibers and the PLA matrix but also filled the interfiber pores, significantly increasing the structural density.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Institute of Chemistry, Federal University of Mato Grosso do Sul, Avenida Senador Filinto Muller 1555, Campo Grande, Mato Grosso do Sul 79074-460, Brazil.
There has been huge interest among chemical scientists in the electrochemical reduction of nitrate (NO) to ammonia (NH) due to the useful application of NH in nitrogen fertilizers and fuel. To conduct such a complex reduction reaction, which involves eight electrons and eight protons, one needs to develop high-performance (and stable) electrocatalysts that favor the formation of reaction intermediates that are selective toward ammonia production. In the present study, we developed and applied CoO/graphene nanoribbon (GNR) electrocatalysts with excellent properties for the effective reduction of NO to NH, where NH yield rate of 42.
View Article and Find Full Text PDFJ Chem Theory Comput
December 2024
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States.
We present an application of our new theoretical formulation of quantum dynamics, moment propagation theory (MPT) (Boyer et al., J. Chem.
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