A triethylene glycol-based 1,2,3-triazolate lithium salt with ionic liquid properties at room temperature is synthesized in three steps including copper-catalysed cycloaddition between alkyne-functionalized monomethoxy-triethylene glycol and azidomethyl pivalate, followed by the deprotection of the methyl pivalate group and further lithiation of the 1H-1,2,3-triazole intermediate. The resulting lithium 1,2,3-triazolate is characterized by NMR spectroscopy, differential scanning calorimetry, thermogravimetric analysis, broadband dielectric spectroscopy, electrochemical impedance spectroscopy and cyclic voltamperometry. This approach provides new opportunities for the further development of highly functional molecular and macromolecular lithium salts.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c8cc04463e | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Impact of the resin cement opacity on the final color of conservative ceramic restorations and on its ability to mask substrates of different saturations.
Dent Mater
January 2025
Department of Biomaterials, School of Dentistry, University of São Paulo, Sao Paulo, Brazil.
Objective: To analyze the impact of the translucency/opacity of two commercial brands of resin cements and different translucency of lithium disilicate on the masking ability of saturated substrates.
Methods: 120 samples (n = 5) were prepared using 0.5 mm lithium disilicate (IPS e.
Solution processable triarylamine-based polyamide for electrochromic supercapacitors and smart displays with energy reuse.
J Colloid Interface Sci
January 2025
College of Materials, Fujian Provincial Key Laboratory of Fire Retardant Materials, Xiamen Key Laboratory of Fire Retardant Materials, Xiamen University, Xiamen 361005, China. Electronic address:
Electrochromic (EC) materials based on ion insertion/desertion mechanisms provide a possibility for energy storage. Solution-processable energy storage EC polyamides have great potential for use in smart displays and EC supercapacitors. A suitable monomer structure design is particularly important for enhancing the electrochemical properties of polyamides.
View Article and Find Full Text PDFHazardous electrolyte releasement and transformation mechanism during water protected spent lithium-ion batteries crushing.
J Hazard Mater
December 2024
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, PR China. Electronic address:
Wet-crushing with aqueous media protection is considered safer and more efficient than common inert-gas protected dry-crushing in preprocessing spent lithium-ion batteries (LIBs). However, it is also accompanied with the releasement and transformation of hazardous electrolyte, while the mechanisms and pollution impact yet remain unknown. Based on a self-built wet-crushing system, this topic was systematically investigated here.
View Article and Find Full Text PDFContinuous Polarizability-Based Separation of Lithium Iron Phosphate and Graphite Using a Dielectrophoretic Particle Separator.
Langmuir
January 2025
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China.
The recovery of valuable materials from spent lithium-ion batteries (LIBs) has experienced increasing demand in recent years. Current recycling technologies are typically energy-intensive and are often plagued by high operation costs, low processing efficiency, and environmental pollution concerns. In this study, an efficient and environmentally friendly dielectrophoresis (DEP)-based approach is proposed to separate the main components of "black mass" mixtures from LIBs, specifically lithium iron phosphate (LFP) and graphite, based on their polarizability differences.
View Article and Find Full Text PDFElectroconvulsive Therapy-Induced Mania in Bipolar Disorder: A Case Report.
Cureus
December 2024
Psychiatry, Psychiatrisch Ziekenhuis Asster, Sint-Truiden, BEL.
Electroconvulsive therapy (ECT) is widely recognized as a safe and effective intervention for treating severe affective episodes in patients with bipolar disorder. However, it can sometimes precipitate unexpected manic phases in patients treated for a depressive episode, a phenomenon known as ECT-induced mania. While this occurrence is recognized, it remains poorly understood and minimally addressed in the literature.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!