Oxytetracycline increases the mobility of carbon nanotubes in porous media.

Unlabelled: The effect of engineered nanoparticles on the mobility of co-existing contaminants has been increasingly studied, while the reverse effect receives little attention. This study provides results from investigating the effect of oxytetracycline (OTC) on the mobility of oxidized multi-walled carbon nanotubes (O-MWCNTs) in quartz sand (QS) columns at various solution ionic strengths (ISs) and pHs. The mobility of O-MWCNTs in QS columns was significantly enhanced by the presence of OTC under all of the tested solution conditions (IS: 0.1, 1.0, and 10mM; pH: 3.0, 5.5, and 8.5), with an increase of 8.6-50.9%. Such enhancement was nonlinear over OTC concentration, which firstly increased (0 to 2.5mgL OTC) and then decreased (2.5 to 20mgLOTC) at pH5.5. The major contributor to the OTC-enhanced O-MWCNTs mobility was competition of the two analytes for adsorption sites on the QS surface. Batch attachment results show that the adsorption of O-MWCNTs in the presence of OTC onto QS was also nonlinear with OTC concentration (firstly decreased and then increased with increasing OTC) at pH5.5, which gave the plausible explanation for the nonlinear enhancement of O-MWCNTs transport in QS columns by the presence of OTC. In turn, both the carrier and competition actions of O-MWCNTs determined the mobility of OTC in QS columns and the carrier action was stronger when more OTC was associated with O-MWCNTs in the influent. These results imply that the mobility of O-MWCNTs in OTC polluted water and soil can be significantly stronger than that in non-polluted area.

Capsule: OTC can increase the migration of O-MWCNTs mainly through the competition for adsorption sites on collectors.