Detonation nanodiamond is a commercially available synthetic diamond that is obtained from the carbon of explosives. It is known that the average particle size of detonation nanodiamond is 4⁻6 nm. However, it is possible to separate smaller particles. Here we suggest a new approach for the effective separation of detonation nanodiamond particles by centrifugation of a "hydrosol/glycerol" system. The method allows for the production of the detonation nanodiamond hydrosol with a very sharp distribution in size, where more than 85% of particles have a size ranging 1⁻4 nm. The result is supported by transmission electron microscopy, atomic force microscopy, and dynamic light scattering.
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http://dx.doi.org/10.3390/ma11081285 | DOI Listing |
Nanomaterials (Basel)
November 2024
Prokhorov General Physics Institute of the Russian Academy of Sciences, 38 Vavilov Str., Moscow 119991, Russia.
Despite progress in the high-pressure synthesis of nanodiamonds from hydrocarbons, the problem of controlled formation of fluorescent impurity centers in them still remains unresolved. In our work, we explore the potential of a new precursor composition, a mixture of adamantane with detonation nanodiamond, both in the synthesis of nanodiamonds and in the controlled formation of negatively charged silicon-vacancy centers in such nanodiamonds. Using different adamantane/detonation nanodiamond weight ratios, a series of samples was synthesized at a pressure of 7.
View Article and Find Full Text PDFMolecules
June 2024
A. N. Bakulev Scientific Center for Cardiovascular Surgery, 135, Rublevskoe Sh., Moscow 121552, Russia.
Coatings with xenogenic materials, made of detonation nanodiamonds, provide additional strength and increase elasticity. A functionally developed surface of nanodiamonds makes it possible to apply antibiotics. Previous experiments show the stability of such coatings; however, studies on stability in the bloodstream and calcification of the material in natural conditions have yet to be conducted.
View Article and Find Full Text PDFNanomaterials (Basel)
March 2024
Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 162 00 Prague, Czech Republic.
The modification of nanodiamond (ND) surfaces has significant applications in sensing devices, drug delivery, bioimaging, and tissue engineering. Precise control of the diamond phase composition and bond configurations during ND processing and surface finalization is crucial. In this study, we conducted a comparative analysis of the graphitization process in various types of hydrogenated NDs, considering differences in ND size and quality.
View Article and Find Full Text PDFChem Rec
April 2024
Department of Chemistry Mirpur, University of Science and Technology (MUST), 10250 (AJK), Mirpur, Pakistan.
Nanodiamonds (NDs) have garnered attention in the field of nanomedicine due to their unique properties. This review offers a comprehensive overview of NDs synthesis methods, properties, and their uses in biomedical applications. Various synthesis techniques, such as detonation, high-pressure, high-temperature, and chemical vapor deposition, offer distinct advantages in tailoring NDs' size, shape, and surface properties.
View Article and Find Full Text PDFRSC Adv
January 2024
Department of Chemistry, University of Liverpool Liverpool L69 7ZD UK
Non-invasive bioimaging is essential in enhancing pre-clinical diagnosis and therapy. Developing efficient imaging probes with high stability, low toxicity, and the potential of offering high resolution images is a very important aspect of developing non-invasive bioimaging techniques. Fluorescent nanodiamonds, which are produced by high energy beam irradiation and high temperature/pressure treatment, have been extensively investigated.
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