There are significant differences in the aggregation mechanisms and types of aggregates that form by oil-particle interactions in marine and laboratory environments depending on the state of oil (i.e., dissolved, emulsified, floating), size and type of particles involved (i.e., colloidal, granular, organic, inorganic), oil-particle interaction mechanisms, and settling/suspension characteristics. Distinct characteristics of oil-particle aggregates that form by interaction of granular particles with floating oil separate them from the well-known oil-colloidal particle aggregates (OcPA), which are sometimes called Pickering emulsions. Unlike OcPA, which involve emulsified oil (entrained oil droplets suspended in the water column) and colloidal particles, the oil-granular particle aggregates (OgPA) involve the floating oil and granular particles. Here, to clarify the differences and similarities between the two types of aggregates (OcPA and OgPA), we present classification of oil aggregates, drawing attention to important characteristics of OcPA, marine oil snow (MOS), and OgPA.
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http://dx.doi.org/10.1016/j.marpolbul.2018.06.037 | DOI Listing |
J Hazard Mater
March 2024
Frontiers Science Center for Deep Ocean Multispheres and Earth System, and Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China. Electronic address:
A quantitative understanding of spilled oil transport in a nearshore environment is challenging due to the complex physicochemical processes in aqueous conditions. The physicochemical processes involved in oil sinking mainly include oil dispersion, sediment settling, and oil-sediment interaction. For the first time, this work attempts to address the sinking mechanism in petroleum contaminant transport using structural causal models based on observed data.
View Article and Find Full Text PDFEnviron Sci Process Impacts
September 2023
College of Environmental Science and Engineering, Dalian Maritime University, Dalian 116026, China.
After an oil spill, the formation of oil-particle aggregates (OPAs) is associated with the interaction between dispersed oil and marine particulate matter such as phytoplankton, bacteria and mineral particles. Until recently, the combined effect of minerals and marine algae in influencing oil dispersion and OPA formation has rarely been investigated in detail. In this paper, the impacts of a species of flagellate algae on oil dispersion and aggregation with montmorillonite were investigated.
View Article and Find Full Text PDFEnviron Sci Technol
May 2023
Frontiers Science Center for Deep Ocean Multispheres and Earth System and Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, People's Republic of China.
Oil spills interact with mineral particles to form oil-particle aggregates (OPAs), which promotes the oil's natural diffusion and biodegradation. We investigated the effect of bacteria on the formation and vertical migration of OPAs under different concentrations and types of particles and proposed and elucidated an oil-particle-bacteria coupling mechanism. The depth of particle penetration into oil droplets (13-17 μm) was more than twice that of the nonbacterial group.
View Article and Find Full Text PDFLangmuir
February 2023
Center for Natural Resources, Civil and Environmental Engineering Department, New Jersey Institute of Technology, Newark, New Jersey 07102, United States.
After an oil spill incident, the spilled oil slicks are observed to migrate to the shoreline area. Under the turbulent conditions, they break into small droplets and are suspended in the water column. The dispersed droplets are expected to interact with the suspended particles and form the oil-particle aggregates (OPAs), which significantly changes the transport of the oil.
View Article and Find Full Text PDFEnviron Sci Process Impacts
March 2023
Department of Civil, Structural and Environmental Engineering, University at Buffalo, The State University of New York, Buffalo, NY, 14260, USA.
Motor oil is one of the most common pollutants in stormwater runoff in freshwater ecosystems. It can form aggregates with solids (creating oil particle aggregates, OPAs) which complicates the understanding of the fate and transport of motor oil, particularly in cold freshwater, conditions that have not been studied extensively. Laboratory and numerical experiments were conducted with kaolinite clay and three types of motor oil in both cold and warm freshwater, in which: (1) the interaction of clay particles with motor oil was experimentally investigated, in response to changes in oil viscosity, water temperature, and mixing intensity; (2) variability in particle size distribution of the formed OPAs was measured; and (3) a mechanistic OPA formation model was applied and results were compared with experimental data.
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