In this work, we found that the side reactions of both the Li anode and cathode with the electrolyte can be obviously alleviated at low temperature. This favorable merit enables long cycle life of the Li-O cells at low temperature. At 0 °C, the cells can sustain stable cycling of 279 and 1025 cycles at 400 mA g with limited capacities of 1000 and 500 mA h g, respectively. Even at -20 °C, the cell can be stably cycled for 83 cycles at 200 mA g with a limited capacity of 500 mA h g.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/acsami.8b06640 | DOI Listing |
Nanomaterials (Basel)
December 2024
The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China.
Developing highly active and durable non-noble metal catalysts is crucial for energy conversion and storage, especially for proton exchange membrane fuel cells (PEMFCs) and lithium-oxygen (Li-O) batteries. Non-noble metal catalysts are considered the greatest potential candidates to replace noble metal catalysts in PEMFCs and Li-O batteries. Herein, we propose a novel type of non-noble metal catalyst (Fe-Hf/N/C) doped with Hf into a mesoporous carbon material derived from Hf-ZIF-8 and co-doping with Fe and N, which greatly enhanced the activity and durability of the catalyst.
View Article and Find Full Text PDFAppl Environ Microbiol
December 2024
Ocean College, Zhejiang University, Zhoushan, China.
This study explored the genomic alterations in , a key yeast in industrial biotechnology, under both spontaneous and mutagen-induced conditions. Our findings reveal that spontaneous mutations occur at a rate of approximately 4 × 10 events per base pair per cell division, primarily manifesting as single-nucleotide variations (SNVs) and small insertions and deletions (InDels). Notably, C-to-T/G-to-A transitions and C-to-A/G-to-T transversions dominate the spontaneous SNVs, while 1 bp deletions, likely resulting from template slippage, are the most frequent InDels.
View Article and Find Full Text PDFAdv Mater
December 2024
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China.
The safety and cycle stability of lithium metal batteries (LMBs) under conditions of high cut-off voltage and fast charging put forward higher requirements for electrolytes. Here, a sulfonate-based deep eutectic electrolyte (DEE) resulting from the eutectic effect between solid sultone and lithium bis(trifluoromethanesulfonyl)imide without any other additives is reported. The intermolecular coordination effect triggers this eutectic phenomenon, as evidenced with nuclear magnetic resonance, and thus the electrochemical behavior of the DEE can be controlled by jointly regulating the coordination effects of F···H and Li···O intermolecular interactions.
View Article and Find Full Text PDFSmall
December 2024
College of Materials and Chemistry, China Jiliang University, Hangzhou, 310018, China.
Biomass with naturally ion-conducting segments (e.g., hydroxyl) holds promise for sustainable batteries.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2024
School of Chemistry, Xi'an Jiaotong University, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an, 710049, P.R. China.
Artificial polymer solid electrolyte interphases (SEIs) with microphase-separated structures provide promising solutions to the inhomogeneity and cracking issues of natural SEIs in lithium metal batteries (LMBs). However, achieving homogeneous ionic conductivity, excellent mechanical properties, and superior interfacial stability remains challenging due to interference from hard-phase domains in ion transport and solid-solid interface issues with lithium metal. Herein, we present a dynamic supramolecular ion-conducting poly (urethane-urea) interphase (DSIPI) that achieves these three properties through modulating the hard-phase domains and constructing a composite SEI in situ.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!