Emission factors of particulate and gaseous compounds from a large cargo vessel operated under real-world conditions.

On-board emissions measurements were performed on a Handysize-class bulk carrier operating under real-world conditions. Emission factors (EFs) were determined for criteria pollutants such as NO, CO, total hydrocarbons (THC), and PM; PM composition, including organic and elemental carbon (OC and EC), inorganic species, and a variety of organic compounds and VOC species (including alkanes, alkenes, single-ring aromatics, and oxygenated VOCs) were also analyzed. To investigate the impacts of engine type, fuel, and operating conditions on emissions, measurements were conducted on one main and one auxiliary engines using low- and high-sulfur fuels (LSF and HSF) under actual operating conditions, including at-berth, maneuvering, and cruising at different engine loads. OC was the most abundant PM component (contributing 45-65%), followed by sulfate (2-15%) and EC (1-20%). Compounds with 3 or 4 aromatic rings, including phenanthrene, fluoranthene, pyrene, and benzo[b+k]fluoranthene, dominated the particulate polycyclic aromatic hydrocarbons (PAHs) emitted from the ship, accounting for 69-89% of the total PAHs. Single-ring aromatics constituted 50-78% of the emitted VOCs and were dominated by toluene. In this study, switching from HSF (1.12% S) to LSF (0.38% S) reduced emitted PM by 12%, OC by 20%, sulfate by 71%, and particulate PAHs by 94%, but caused an increase in single-ring aromatics. The power-based EFs generally decreased with increasing engine loads. However, decreasing the ship engine load also reduced the vessel speed and, thus, decreased emissions over a given voyage distance. Herein, a Vessel Speed Reduction (VSR) from 11 to 8-9 knots decreased NO and PM emissions by approximately 33% and 36%, respectively, and OC, EC, sulfate, and particulate PAHs in PM emissions by 34%, 83%, 29%, and 11%. These data can be used to minimize uncertainty in the emission factors used in ship emissions calculations.