Two-Dimensional BiWO Nanosheets as a Robust Catalyst toward Photocyclization.

The present work describes the improved photocatalytic activity of cetyl trimethylammonium bromide (CTAB)-assisted BiWO (CBTH) toward the synthesis of bioactive benzazoles. X-ray diffraction analysis of CBTH suggests that crystal growth has occurred along the (200) plane, whereas field-emission scanning electron microscopy images confirm two-dimensional rose bud morphology and high-resolution transmission electron microscopy analysis suggests the formation of thin nanosheets possessing an orthorhombic structure. Temperature-programmed desorption of ammonia and Py-IR measurements indicate substantial acidity with the generation of Brønsted acid sites on the surface of CBTH. Raman spectra of CBTH also corroborate these observations with the formation of defects within [BiO] layers, resulting in decreased thickness and shapes of nanoplates. These beneficial properties are explored toward the photochemical synthesis of benzazoles using a 35 W tungsten lamp and a CBTH photocatalyst, resulting in better yields at lesser exposure time. It is observed that the catalytic activity is retained up to five consecutive cycles with marginal decrease in % yield. Such a feature can be ascribed to the photostability of the photocatalyst even after continuous exposure to light, implying that the surface active sites remained unaltered as evident from the X-ray photoelectron spectroscopy analysis of pre- and post-characterization of CBTH. Moreover, decrease in the surface hydroxyl groups after five catalytic cycles also accounts for the generation of enhanced Brønsted sites owing to the presence of Bi-O on the surface of CBTH. It exhibits better catalytic activity as compared to other photocatalysts employed for the synthesis of benzazoles. Thus, CBTH serves as a robust photocatalyst for the facile synthesis of these heterocycles in a sustainable manner.