AI Article Synopsis
- The text discusses the first crystal structure of a neptunium-rotaxane complex, named NRCP-1, which expands previous research on actinide-rotaxane complexes from uranium to transuranium elements.
- This complex features a unique coordination network where neptunium(V) is interwoven with a mechanically-interlocked daisy chain unit.
- The formation of this structure is facilitated by the coordination of two key elements: cucurbituril (CB6) and axle molecules within the pseudorotaxane framework.
Article Abstract
As an extension of actinide-rotaxane complexes from uranium to transuranium, we report the first crystal structure of a neptunium-rotaxane complex, NRCP-1, in which an interwoven neptunium(v)-rotaxane coordination network incorporating a mechanically-interlocked [c2]daisy chain unit is promoted via the simultaneous coordination of cucurbituril (CB6) and axle molecules in [2]pseudorotaxane to Np.
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| http://dx.doi.org/10.1039/c8cc05122d | DOI Listing |
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