A chiral porous 3D metal-organic framework (MOF) is constructed from an enantiopure carboxylate ligand of 1,1'-biphenol, which can be utilized as adsorbent for the separation of aromatic alcohols and sulfoxides with enantioselectivity of up to 99.4%. Single-crystal X-ray diffraction analysis reveals the binding sites and host-guest interactions clearly, providing microscopic insight into the origin of the enantiosorption in the framework.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.inorgchem.8b00948 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
RETRACTED: Ahmed et al. Thermal Analysis of a Metal-Organic Framework ZnxCo-ZIF-8 for Recent Applications. 2021, , 4051.
Polymers (Basel)
December 2024
Chemistry Department, Faculty of Science, New Valley University, Kharga 11765, Egypt.
The journal retracts the article "Thermal Analysis of a Metal-Organic Framework ZnxCo1-X-ZIF-8 for Recent Applications" [...
View Article and Find Full Text PDFA Comprehensive Review of Multifunctional Nanozymes for Degradation and Detection of Organophosphorus Pesticides in the Environment.
Toxics
December 2024
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Organophosphorus pesticides are the most extensively utilized agrichemicals in the world. They play a crucial role in regulating crop growth, immunizing against pests, and improving yields, while their unregulated residues exert serious detrimental effects on both the environment and human health. Many efforts have been made in the world to monitor organophosphorus pesticides and solve the issues caused by them.
View Article and Find Full Text PDFRecent Advancements in CoO-Based Composites for Enhanced Electrocatalytic Water Splitting.
Micromachines (Basel)
November 2024
Department of Fiber System Engineering, Yeungnam University, 280 Dehak-Ro, Gyeongsan 38541, Republic of Korea.
The pursuit of efficient and economical catalysts for water splitting, a critical step in hydrogen production, has gained momentum with the increasing demand for sustainable energy. Among the various electrocatalysts developed to date, cobalt oxide (CoO) has emerged as a promising candidate owing to its availability, stability, and catalytic activity. However, intrinsic limitations, including low catalytic activity and poor electrical conductivity, often hinder its effectiveness in electrocatalytic water splitting.
View Article and Find Full Text PDFDFT Approach for Predicting C NMR Shifts of Atoms Directly Coordinated to Pt: Scopes and Limitations.
Molecules
December 2024
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.
In this study, comparative analysis of calculated and experimental C NMR shifts for a wide range of model platinum complexes showed that, on the whole, the theory reproduces the experimental data well. The chemical shifts of carbon atoms directly bonded to Pt can be calculated well only within the framework of the fully relativistic matrix Dirac-Kohn-Sham (mDKS) level ( = 0.9973, = 3.
View Article and Find Full Text PDFModifications and Applications of Metal-Organic-Framework-Based Materials for Photocatalysis.
Molecules
December 2024
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China.
Metal-organic frameworks (MOFs) represent a category of crystalline materials formed by the combination of metal ions or clusters with organic linkers, which have emerged as a prominent research focus in the field of photocatalysis. Owing to their distinctive characteristics, including structural diversity and configurations, significant porosity, and an extensive specific surface area, they provide a flexible foundation for various potential applications in photocatalysis. In recent years, researchers have tackled many issues in the MOF-based photocatalytic yield.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!