Driven Widom-Rowlinson lattice gas.

Phys Rev E

Center for Soft Matter and Biological Physics, Department of Physics, Virginia Polytechnic Institute & State University, Blacksburg, Virginia 24061, USA.

Published: June 2018

In the Widom-Rowlinson lattice gas, two particle species (A, B) diffuse freely via particle-hole exchange, subject to both on-site exclusion and prohibition of A-B nearest-neighbor pairs. As an athermal system, the overall densities are the only control parameters. As the densities increase, an entropically driven phase transition occurs, leading to ordered states with A- and B-rich domains separated by hole-rich interfaces. Using Monte Carlo simulations, we analyze the effect of imposing a drive on this system, biasing particle moves along one direction. Our study parallels that for a driven Ising lattice gas, the Katz-Lebowitz-Spohn (KLS) model, which displays atypical collective behavior, e.g., structure factors with discontinuity singularities and ordered states with domains only parallel to the drive. Here, other interesting features emerge, including structure factors with kink singularities (best fitted to |q|), maxima at nonvanishing wave-vector values, oscillating correlation functions, and ordering into multiple striped domains perpendicular to the drive, with a preferred wavelength depending on density and drive intensity. Moreover, the (hole-rich) interfaces between the domains are statistically rough (whether driven or not), in sharp contrast with those in the KLS model, in which the drive suppresses interfacial roughness. Defining an order parameter that accounts for the emergence of multistripe states, we map out the phase diagram in the density-drive plane and present preliminary evidence for a critical phase in this driven lattice gas.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevE.97.062126DOI Listing

Publication Analysis

Top Keywords

lattice gas
16
widom-rowlinson lattice
8
ordered states
8
hole-rich interfaces
8
kls model
8
structure factors
8
driven
5
drive
5
driven widom-rowlinson
4
lattice
4

Similar Publications

Zinc oxide nanoparticles (ZnO NPs) with varying levels of nitrogen (N) doping were synthesized using a straightforward sol-gel approach. The morphology and microstructure of the N-doped ZnO NPs were examined through techniques such as SEM, XRD, photoluminescence, and Raman spectroscopy. The characterization revealed visible changes in the morphology and microstructure resulting from the incorporation of nitrogen into the ZnO lattice.

View Article and Find Full Text PDF

Heterojunctions, known for their decent separation of photo-generated electrons and holes, are promising for photocatalytic CO reduction. However, a significant obstacle in traditional post-assembled heterojunctions is the high interfacial barrier for charge transfer caused by atomic lattice mismatch at multiphase interfaces. Here, as research prototypes, the study creates a lattice-matched co-atomic interface within CsPbBr-CsPbBr polytypic nanocrystals (113-125 PNs) through the proposed in situ hybrid strategy to elucidate the underlying charge transfer mechanism within this unique interface.

View Article and Find Full Text PDF

Engineering Lattice Dislocations of TiO Support of PdZn-ZnO Dual-Site Catalysts to Boost CO Hydrogenation to Methanol.

Angew Chem Int Ed Engl

December 2024

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Haihe Laboratory of Sustainable Chemical Transformations, Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering & Technology, Tianjin University, Tianjin, 300072, P. R. China.

CO hydrogenation to methanol using green hydrogen derived from renewable resources provides a promising method for sustainable carbon cycle but suffers from high selectivity towards byproduct CO. Here, we develop an efficient PdZn-ZnO/TiO catalyst by engineering lattice dislocation structures of TiO support. We discover that this modification orders irregularly arranged atoms in TiO to stabilize crystal lattice, and consequently weakens electronic interactions with supported active phases.

View Article and Find Full Text PDF

Photocatalytic asymmetric C-C coupling for CO reduction on dynamically reconstructed Ru-O/Ru-O sites.

Nat Commun

January 2025

Department of Chemical and Petroleum Engineering, University of Calgary, 2500 University Drive, NW, Calgary, AB, Canada.

Solar-driven CO reduction to value-added C chemicals is thermodynamically challenging due to multiple complicated steps. The design of active sites and structures for photocatalysts is necessary to improve solar energy efficiency. In this work, atomically dispersed Ru-O sites in RuInO are constructed by interior lattice anchoring of Ru.

View Article and Find Full Text PDF

The concept of non-Hermiticity has expanded the understanding of band topology, leading to the emergence of counter-intuitive phenomena. An example is the non-Hermitian skin effect (NHSE), which involves the concentration of eigenstates at the boundary. However, despite the potential insights that can be gained from high-dimensional non-Hermitian quantum systems in areas such as curved space, high-order topological phases and black holes, the realization of this effect in high dimensions remains unexplored.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!