We study the crossover from low-temperature to high-temperature fluctuations including Goldstone-dominated and critical fluctuations in confined isotropic and weakly anisotropic O(n)-symmetric systems on the basis of a finite-size renormalization-group approach at fixed dimension d introduced previously [V. Dohm, Phys. Rev. Lett. 110, 107207 (2013)PRLTAO0031-900710.1103/PhysRevLett.110.107207]. Our theory is formulated within the φ^{4} lattice model in a d-dimensional block geometry with periodic boundary conditions. We calculate the finite-size scaling functions F^{ex} and X of the excess free-energy density and the thermodynamic Casimir force, respectively, for 1≤n≤∞, 2
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http://dx.doi.org/10.1103/PhysRevE.97.062128 | DOI Listing |
Nat Commun
January 2025
Department of Computational Biology, Cornell University, Ithaca, 14853, NY, USA.
A major goal of cancer biology is to understand the mechanisms driven by somatically acquired mutations. Two distinct methodologies-one analyzing mutation clustering within protein sequences and 3D structures, the other leveraging protein-protein interaction network topology-offer complementary strengths. We present NetFlow3D, a unified, end-to-end 3D structurally-informed protein interaction network propagation framework that maps the multiscale mechanistic effects of mutations.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Synthesis of 2D quasi-hexagonal phase C (qHP C) has opened avenues for its application as a novel catalytic support. This study investigates the structure, stability, and anisotropic properties of Cu clusters anchored on the qHP C surface through density functional theory calculations. Our findings reveal that the Cu cluster preferentially occupies the intrinsic holes of the qHP C via one of its tetrahedral faces, resulting in enhanced stability and conductivity, with a significantly reduced band gap of 0.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan. Electronic address:
Starch-derived hydrophilic malto-oligosaccharides (Glc, where n = 1-7) conjugated to hydrophobic solanesol through click chemistry, i.e., Glc-b-Sol copolymers, have demonstrated significant promise in developing fully natural block co-oligomers for solid-state nanopatterning applications.
View Article and Find Full Text PDFSoft Matter
January 2025
Department of Chemical and Biomolecular Engineering, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA.
In polymerization-induced phase separation, the impact of polymer-substrate interaction on the dynamics of phase separation for polymer blends is important in determining the final morphology and properties of polymer materials as the surface can act as another driving force for phase separation other than polymerization. We modify the previously-developed polymerizing Cahn-Hilliard (pCH) method by adding a surface potential to model the phase separation behavior of a mixture of two species independently undergoing linear step-growth polymerization in the presence of a surface. In our approach, we explicitly model polydispersity by separately considering different molecular-weight components with their own respective diffusion constants, and with the surface potential preferentially acting on only one species.
View Article and Find Full Text PDFNat Commun
January 2025
Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, China.
Inspired by counterintuitive water "swelling" ability of the hydrophobic moss of the genus Sphagnum (Peat moss), we prepared a hydrophobic pseudo-hydrogel (HPH), composed of a pure hydrophobic silicone elastomer with a tailored porous structure. In contrast to conventional hydrogels, HPH achieves absorption-induced volume expansion through surface tension induced elastocapillarity, presenting an unexpected absorption-induced volume expansion capability in hydrophobic matrices. We adopt a theoretical framework elucidating the interplay of surface tension induced elastocapillarity, providing insights into the absorption-induced volume expansion behavior.
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