Possible universal relation between short time β-relaxation and long time α-relaxation in glass-forming liquids.

J Chem Phys

Centre for Interdisciplinary Sciences, Tata Institute of Fundamental Research, 36/P, Gopanpally Village, Serilingampally Mandal, Ranga Reddy District, Hyderabad 500107, India.

Published: July 2018

Relaxation processes in supercooled liquids are known to exhibit interesting complex behavior. One of the hallmarks of this relaxation process observed in the measured auto correlation function is the occurrence of multiple steps of relaxations. The shorter time relaxation is known as the β-relaxation which is believed to be due to the motion of particles in the cage formed by their neighbors. The longer time relaxation is called the α-relaxation. The time scales of these two relaxations processes dramatically separate out with supercooling. In spite of decades of research, it is still not clearly known how these relaxation processes are related to each other. In this work, we show that there is a possible universal relation between short time β-relaxation and long time α-relaxation. We also show that the proposed relation can be rationalized within random first order transition theory of glass transition if power law relation is assumed between static and dynamic length scales.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.5033555DOI Listing

Publication Analysis

Top Keywords

universal relation
8
relation short
8
short time
8
time β-relaxation
8
β-relaxation long
8
long time
8
time α-relaxation
8
relaxation processes
8
time relaxation
8
time
7

Similar Publications

Background And Aims: An expansion of fat mass is an integral feature of patients with heart failure and preserved ejection fraction (HFpEF). While body mass index (BMI) is the most common anthropometric measure, a measure of central adiposity-the waist-to-height ratio (WHtR)-focuses on body fat content and distribution; is not distorted by bone or muscle mass, sex, or ethnicity; and may be particularly relevant in HFpEF.

Methods: The PARAGON-HF trial randomized 4796 patients with heart failure and ejection fraction ≥45% to valsartan or sacubitril/valsartan.

View Article and Find Full Text PDF

Background: Most maternal deaths are preventable by accessing essential maternity healthcare services. However, maternal mortality rates remain high in Ethiopia partly due to only a few women using a complete Continuum of Maternal Healthcare Services (CMHS). This study aims to assess trends and contributors for complete CMHS utilization in Ethiopia.

View Article and Find Full Text PDF

Background: A number of genetic aberrations are associated with the BCL6-correpresor gene (BCOR), including internal tandem duplications (ITDs) and gene fusions (BCOR::CCNB3 and BCOR::MAML3), as well as YWHAE::NUTM2, which are found in clear cell sarcoma of the kidney (CCSK), sarcoma with BCOR genetic alterations, primitive myxoid mesenchymal tumor of infancy, and high-grade neuroepithelial tumors in children. Detecting these gene aberrations is crucial for tumor diagnosis. ITDs can be identified by Sanger sequencing or agarose gel electrophoresis.

View Article and Find Full Text PDF

Background: China has made strides to achieve universal pension coverage through implementing the Public Pension Scheme for Urban and Rural Residents (PPSURR) program since 2014. This study explores the effectiveness of implementing the PPSURR in an impoverished county in China and investigates the determinants of residents' choice on the contribution level of the PPSURR.

Methodology: Binary logit regression models were conducted using datasets extracted from the Chinese General Social Survey in 2021 and datasets collected through surveying 321 residents in Donglan county, China.

View Article and Find Full Text PDF

Nanoization of Technical Pesticides: Facile and Smart Pesticide Nanocapsules Directly Encapsulated through "On Site" Metal-Polyphenol Coordination Assembly for Improved Efficacy and Biosafety.

J Agric Food Chem

January 2025

State Key Laboratory of Coordination Chemistry, Key Laboratory of Mesoscopic Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.

Facile pesticide nanocapsules were successfully prepared by directly encapsulating the antisolvent precipitation of pesticides through instantaneous "on site" coordination assembly of tannic acid and Fe, avoiding tedious preparation, time consumption, and large amounts of organic solvents. The pesticide nanocapsules showed excellent resistance to ultraviolet photolysis and rainwater washing owing to the nanocapsule walls. The smart pesticide nanocapsules exhibited the controlled release of pesticides under multidimensional stimuli, such as acidic/alkaline pH, glutathione, HO, phytic acid, laccase, tannase, and sunlight, which were related to the physiological and natural environments of crops, pests, and pathogens.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!