Construction of spirocarbocycles gold-catalyzed intramolecular dearomatization of naphthols.

Chem Sci

State Key Laboratory of Organometallic Chemistry , Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Lu , Shanghai 200032 , China . Email:

Published: May 2016

A highly efficient, gold-catalyzed intramolecular dearomatization reaction of naphthols 5- cyclization is described. This facile and direct approach furnishes spirocarbocycles in excellent yields under mild conditions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006865PMC
http://dx.doi.org/10.1039/c5sc04130aDOI Listing

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