Q-band electron paramagnetic resonance (EPR) data conclusively demonstrate that the iron and cobalt centers in the solid solution [Fe(bpp)][Co(terpy)][BF] (bpp = 2,6-dipyrazol-1-ylpyridine) undergo allosteric spin-state switching during light-induced excited-spin-state trapping (LIESST) at 20 K and thermal relaxation around 80 K. EPR of [Cu(terpy)] and [Cu(bpp)], doped into the same host lattice, also indicates expansion of the copper coordination sphere during LIESST excitation.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.inorgchem.8b01096 | DOI Listing |
Publication Analysis
Top Keywords
host lattice
8
light-induced excited-spin-state
8
excited-spin-state trapping
8
electron paramagnetic
8
paramagnetic resonance
8
interplay dopant
4
dopant species
4
species spin-crossover
4
spin-crossover host
4
lattice light-induced
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!