A novel gold-catalyzed tandem protocol, initiated by hydride transfer in the presence of catalytic (C F ) PAuCl/AgSbF , for the formation of fused polycyclic ring systems has been achieved. This tandem reaction provides rapid access to various fused polycyclic species in a single chemical operation, leading to stereospecific formation of two carbon-carbon bonds and three rings.
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| http://dx.doi.org/10.1002/anie.201806842 | DOI Listing |
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