Microbial fuel cell (MFC) technology has potential in recovering bioelectricity from different types of waste, which attracts more and more attention in the field of environment and energy. However, low power density, high cost and low substrate degradation rate, closely associated with anode performance, limit its practical application. In this study, proportional polyaniline (PANI) together with graphene was chosen to obtain the PANI dopped graphene composite. The as-received composite was modified onto the surface of glassy carbon electrode. The results of electrochemical analysis showed that the optimal mass ratio of graphene was 20% for cyclic voltammetry (CV) and linear sweep voltammetry (LSV) analysis. The anodes with 5% graphene produced a peak power density of (831±45) mW·m, which was 1.2, 1.3, 1.3, 1.5, 1.8 times of those with 20% graphene, 1% graphene, graphene, PANI and carbon cloth, respectively. Moreover, 5% graphene reactors showed the maximum values in output voltage, open-circuit voltage (OCV), chemical oxygen demand (COD) removal rate, coulombic efficiency (CE), and biomass density. The polarization resistance was only (24±2)Ω in 5% graphene reactors,which was 19.8% of that of carbon cloth. The results of electrochemical analysis were not consistent with those of bioelectrochemical analysis, demonstrating that the biocompatibility of electrode was one of the important factors affecting MFC performance. 5% graphene anode showed full advantages of graphene and PANI, which improved the performance of MFC.
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http://dx.doi.org/10.13227/j.hjkx.201609062 | DOI Listing |
Acc Chem Res
January 2025
Helmholtz Institute Ulm (HIU) Electrochemical Energy Storage, Helmholtzstrasse 11, 89081 Ulm, Germany.
ConspectusLithium-ion batteries (LIBs) based on graphite anodes are a widely used state-of-the-art battery technology, but their energy density is approaching theoretical limits, prompting interest in lithium-metal batteries (LMBs) that can achieve higher energy density. In addition, the limited availability of lithium reserves raises supply concerns; therefore, research on postlithium metal batteries is underway. A major issue with these metal anodes, including lithium, is dendritic formation and insufficient reversibility, which leads to safety risks due to short circuits and the use of flammable electrolytes.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, Devchand College, Arjunnagar, Kolhapur, MH, 591237, India.
Acoustical properties are essential for understanding the molecular interactions in fluids, as they influence the physicochemical behavior of liquids and determine their suitability for diverse applications. This study investigated the acoustical parameters of silver nanoparticles (Ag NPs), reduced graphene oxide (rGO), and Ag/rGO nanocomposite nanofluids at varying concentrations. Ag NPs and Ag/rGO nanocomposites were synthesized via a Bos taurus indicus (BTI) metabolic waste-assisted method and characterized using advanced techniques, including XRD, TEM, Raman, DLS, zeta potential, and XPS.
View Article and Find Full Text PDFNat Commun
January 2025
School of Physical Science and Technology, Ningbo University, Ningbo, 315211, China.
The high performance of two-dimensional (2D) channel membranes is generally achieved by preparing ultrathin or forming short channels with less tortuous transport through self-assembly of small flakes, demonstrating potential for highly efficient water desalination and purification, gas and ion separation, and organic solvent waste treatment. Here, we report the construction of vertical channels in graphene oxide (GO) membrane based on a substrate template with asymmetric pores. The membranes achieved water permeance of 2647 L m h bar while still maintaining an ultrahigh rejection rate of 99.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Institute for Advanced Study (IAS), College of Life Sciences and Oceanography, Shenzhen University, Shenzhen, Guangdong, 518060, China. Electronic address:
Background: Alzheimer's disease (AD) is a neurodegenerative disorder with a very long duration, posing a serious threat to people's life and health. To date, no medicine that can cure or reverse the disease has been developed or reported, so early diagnosis and timely intervention are essential. The concentration of Phosphorylated tau181 (P-tau181) in blood has been approved by FDA as a standard for assisting clinical diagnosis of AD.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, PR China; Department of Chemistry, Sungkyunkwan University, Suwon, 16419, Republic of Korea. Electronic address:
Background: Estriol (E3) is a common estrogen responsible for regulating the female reproductive system, but excessive amount can pose health risks to humans and wild life. Therefore, sensitive and accurate detection of estriol level is crucial. A novel competitive ECL immunosensor based on a dual signal amplification strategy of AuNPs@GO@SmMoSe and Gd(MoO) was fabricated for ultrasensitive detection of estriol.
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