8 surface sediments and 8 water samples were collected from the Daye Lake in August 2015.The 16 kinds of EPA control polycyclic aromatic hydrocarbons (PAHs) were analyzed by GC-MS.The results showed that the PAHs concentrations of surface sediments and water ranged from 35.94 ng·g to 2032.73 ng·g and from 27.94 ng·L to 242.95 ng·L,with average contents of 940.61 ng·g and 107.77ng·L,respectively.The distribution of PAHs in surface sediments indicated that the contents in the center samples were higher than those in the bank samples,but the water showed nearly the opposite tendency.The 4-5 rings high molecular weight PAHs were the main components in the surface sediments,and the 2,4 and 5 rings PAHs were given priority in water.Compared with the other domestic and oversea lakes,the PAHs pollution of the Daye Lake was at a moderate level.Source apportionment showed that the PAHs in surface sediments and water from the Daye Lake came from the combustion source,HWM-PAHs were the dominant part of the PAHs in the sediment,reflecting the sediment PAHs pollution under the effects of mining and smelting over a long period;All monomer PAHs and total PAHs content in sediment did not exceed the ERM and FEL limiting values,showing that there was no particularly serious ecological risk caused by PAHs in the surface sediments from the Daye Lake;the incremental lifetime cancer risks assessment showed that the uptake risk of PAHs in Daye Lake water through the ingestion and dermal absorption were both in the acceptable range recommended by the USEPA,but all sites had higher risk than the acceptable risk level recommended by the Sweden environmental protection agency and Royal society.The pollution of seven carcinogenic PAHs needs prevention and control.
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http://dx.doi.org/10.13227/j.hjkx.201606058 | DOI Listing |
Environ Sci Technol
January 2025
Department of Chemistry and Biochemistry, Concordia University, Montreal, Quebec H4B 1R6, Canada.
Coal tar-related products as a source of polycyclic aromatic compounds (PACs) are particularly concerning due to high PAC concentrations and inadequate source management. Benzo[b]carbazole, a benzocarbazole isomer exclusively found in coal tar-derived products, acts as an ideal marker to distinguish coal tar sources from others, enabling more robust quantification of coal tar contributions to PACs. To evaluate the historical and recent contributions of coal tar-related sources to the levels of PACs in Lake Ontario and associated ecological risk, we analyzed 31 PACs and 3 BCBz isomers in surface sediments and a sediment core.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Department of Environmental Systems Science, ETH Zürich, Zürich 8092, Switzerland.
When microplastics (MPs) enter water bodies, they undergo various transport processes, including sedimentation, which can be influenced by factors such as particle size, density, and interactions with other particles. Surface waters contain suspended natural particles (e.g.
View Article and Find Full Text PDFNat Commun
January 2025
Laboratoire des Sciences du Climat et de l' Environnement, LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France.
Organic carbon burial (OCB) in lakes, a critical component of the global carbon cycle, surpasses that in oceans, yet its response to global warming and associated feedbacks remains poorly understood. Using a well-dated biomarker sequence from the southern Tibetan Plateau and a comprehensive analysis of Holocene total organic carbon variations in lakes across the region, here we demonstrate that lake OCB significantly declined throughout the Holocene, closely linked to changes in temperature seasonality. Process-based land surface model simulations clarified the key impact of temperature seasonality on OCB in lakes: increased seasonality in the early Holocene saw warmer summers enhancing ecosystem productivity and organic matter deposition, while cooler winters improved organic matter preservation.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Shanxi Key Laboratory of Sorghum Genetic and Germplasm Innovation, Sorghum Research Institute, Shanxi Agricultural University, Jinzhong 030600, China.
The partitioning and migrating of antibiotic residues pose a considerable pollution to the river environment. However, a source-specific approach for quantifying the fate of antibiotics is lacking. To further elucidate the migration behavior of antibiotics from different pollution sources in aquatic environments, we introduced a source-specific partition coefficient (S-Kp) based on Positive Matrix Factorization (PMF) model to improve the multimedia model.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Chemistry and Environment, Guangdong Provincial Observation and Research Station for Tropical Ocean Environment in Western Coastal Water, Guangdong Ocean University, Zhanjiang 524088, China.
Microplastic pollution, a major global environmental issue, is gaining heightened attention worldwide. Marginal seas are particularly susceptible to microplastic contamination, yet data on microplastics in marine sediments remain scarce, especially in the Beibu Gulf. This study presents a large-scale investigation of microplastics in the surface sediments of the Beibu Gulf to deciphering their distribution, sources and risk to marginal seas ecosystems.
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