In order to reveal the influence of anthropogenic factors on soil environment quality, a total of seventy-seven samples in topsoils were collected from Jiaojia gold mining area in Shandong province and were determined for Cu, Pb, Zn, Cr contents. Spatial structure, spatial distributions of concentrations and risk probability of heavy metals were analyzed using spatial statistic analysis. The average concentrations of Cu, Pb, Zn and Cr were 19.41 mg·kg, 27.32 mg·kg, 49.81 mg·kg and 39.27 mg·kg, respectively. Pb, Zn and Cr were distributed normally and Cu was distributed normally after logarithm transformation. Semivariance analysis demostrated that Pb could be fitted to exponential model, and Cu, Zn and Cr were fit for spherical model. Nugget coefficents of Cu and Pb were between 0.25 and 0.75, which illustrated middle spatial autocorrelation; Zn and Cr showed the structural variation with nugget values below 0.25. Cu and Pb in the topsoils were distributed dispersedly due to effects of some human factors, whereas contents of Zn and Cr indicated relatively regular distributions and were mainly affected by natural factors. Spatial distributions of the 4 heavy metals were approximately consisitent and the high value areas appeared in the gold mines band. The result of hot spot analysis and indicator kriging interpolation revealed that the relatively high risk areas were located in Jincheng town, the boundary zone of Xinzhuang town and Canzhuang town, while the safe zone was situated in south part of the study area. Pb had higher probability exceeding the threshold and the middle or high environmental risk areas of Pb were distributed widely, which should be paid more attentions.
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http://dx.doi.org/10.13277/j.hjkx.2016.08.041 | DOI Listing |
Crit Rev Anal Chem
January 2025
Department of Chemistry, University of Delhi, New Delhi, India.
Heavy metal pollution is a major environmental and health problem due to the toxicity and persistence of metals such as lead, mercury, cadmium, and arsenic in water, soil, and air. Advances in sensor technology have significantly improved the detection and quantification of heavy metals, providing real-time monitoring and mitigation tools. This review explores recent developments in heavy metal detection, focusing on innovative uses of immobilized chromogenic reagents, nanomaterials, perovskites, and nanozymes.
View Article and Find Full Text PDFPlant Physiol Biochem
January 2025
Centre for Nanobiotechnology, Vellore Institute of Technology, Vellore, Tamil Nadu, India. Electronic address:
The accumulation of disposable face masks (DFMs) has become a significant threat to the environment due to extensive use during the COVID-19 pandemic. In this research, we investigated the degradation of DFMs after their disposal in landfills. We replicated the potential degradation process of DFMs, including exposure to sunlight before subjecting them to synthetic landfill leachate (LL).
View Article and Find Full Text PDFTalanta
December 2024
Institute of Atomic and Molecular Physics, Jilin University, Changchun, 130012, China. Electronic address:
Laser-induced breakdown spectroscopy (LIBS) is a rapidly evolving in-situ multi-element analysis technique that has significantly advanced the field of liquid analysis. This study employs a femtosecond laser for quantitative analysis of heavy metals in flowing liquids, exploring its detection sensitivity and accuracy. Femtosecond pulsed laser excitation of water in a dynamic environment generates plasma while effectively preventing liquid splashing.
View Article and Find Full Text PDFTalanta
January 2025
College of Chemistry and Materials Science, Hunan Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, Hengyang Normal University, Hengyang, 421001, China. Electronic address:
The accurate and sensitive quantification of hydroxyl radical (·OH) and glucose is necessary for disease diagnosis and health guidance, but still challenging owing to the low concentration of ·OH and poor water solubility of fluorescent probes. In addition, fluorescent probes may cause secondary pollution to the environment. Here an organic cage was reported as a sensitive fluorescent probe for ·OH and glucose in aqueous solution without serious secondary pollution.
View Article and Find Full Text PDFFood Chem
December 2024
Department of Chemistry, Faculty of Sciences, Erciyes University, Kayseri, Turkiye; Technology Research and Application Center (TAUM), Erciyes University, Kayseri, Turkiye; Turkish Academy of Sciences (TUBA), Cankaya, Ankara, Turkiye; Khazar University Nano BioAnalytical Chemistry Center (NBAC), Mahsati Str 41, AZ-1096 Baku, Azerbaijan.
In this study, a green synthesis method for synthesizing a novel nanocomposite (CuO/g-C₃N₄/Fe₃O₄) utilizing renewable dragon fruit peels as the primary raw material was developed. Hydrothermal and thermal decomposition techniques were used for nanocomposite synthesis. This nanocomposite was subsequently employed for the separation and preconcentration of Cd(II) from various environments, including food and water samples.
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