Sensitive trace gas detection plays an important role in current challenges occurring in areas such as industrial process control and environmental monitoring. In particular, for medical breath analysis and for the detection of illegal substances, e.g., drugs and explosives, a selective and sensitive detection of trace gases in real-time is required. We report on a compact and transportable multi-component system (RES-Q-Trace) for molecular trace gas detection based on cavity-enhanced techniques in the mid-infrared (MIR). The RES-Q-Trace system can operate four independent continuous wave quantum or interband cascade lasers each combined with an optical cavity. Twice the method of off-axis cavity-enhanced absorption spectroscopy (OA-CEAS) was used, twice the method of optical feedback cavity-enhanced absorption spectroscopy (OF-CEAS), respectively. Multi-functional software has been implemented (i) for the general system control; (ii) to drive the four different laser sources and (iii) to analyze the detector signals for concentration determination of several molecular species. For the validation of the versatility and the performance of the RES-Q-Trace instrument the species NO, N₂O, CH₄, C₂H₄ and C₃H₆O, with relevance in the fields of breath gas analysis and the detection of explosives have been monitored in the MIR with detection limits at atmospheric pressure in the ppb and ppt range
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http://dx.doi.org/10.3390/s18072058 | DOI Listing |
Sci Total Environ
January 2025
Université Paris Cité - Institut de Physique du globe de Paris, CNRS, F75005 Paris, France.
Nanoparticles (NPs) exhibit high reactivity and mobility in the environment, and a significant capacity to penetrate living organisms, potentially leading to harmful effects. Volcanoes are the second major source of natural NPs emitted into the atmosphere, with an estimated flux of 342 Tg/year. Few studies have focused on their fate.
View Article and Find Full Text PDFJ Pharm Biomed Anal
January 2025
Key Laboratory of Forensic Medicine, Ministry of Justice, Shanghai Forensic Service Platform, Shanghai Key Laboratory of Forensic Science, Academy of Forensic Science, Guangfu West Road 1347, Shanghai 200063, China. Electronic address:
Etomidate and its structural analogues, which have anesthetic effects, are classified as controlled psychotropic drugs. Electronic cigarettes (e-cigarettes) have become more and more popular. With the increase of adding etomidate and its analogues to electronic liquids (e-liquids), there is a trend of abuse, which is a tough problem urgently need to be solved.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Dublin City University, School of Electronic Engineering, 9, Dublin, Ireland.
Exogenous nitrogen supplementation for the bioremediation of petroleum-contaminated soils is a widely adopted and effective environmentally friendly strategy. However, the mechanism by which varying nitrogen dosages affect hydrocarbon degradation pathways remains unclear. This study conducted bioremediation on soil with a total petroleum hydrocarbon (TPH) content of 17,090 mg/kg over 210 days.
View Article and Find Full Text PDFNew Phytol
January 2025
Centre of Excellence PLECO (Plants and Ecosystems), Department of Biology, University of Antwerp, Universiteitsplein 1, B-2610, Wilrijk, Belgium.
Recent studies have shown that stem fluxes, although highly variable among trees, can alter the strength of the methane (CH) sink or nitrous oxide (NO) source in some forests, but the patterns and magnitudes of these fluxes remain unclear. This study investigated the drivers of subdaily and seasonal variations in stem and soil CH, NO and carbon dioxide (CO) fluxes. CH, NO and CO fluxes were measured continuously for 19 months in individual stems of two tree species, Eperua falcata (Aubl.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Xiamen University, Chemistry, No. 422, Simingnan Road, 361005, Xiamen, CHINA.
The presence of trace CO impurity gas in hydrogen fuel can rapidly deactivate platinum-based hydrogen oxidation reaction (HOR) catalysts due to poisoning effects, yet the precise CO tolerance mechanism remains debated. Our designed Au@PtX bifunctional core-shell nanocatalysts exhibit excellent performance of CO tolerance in acidic solution during HOR and possess exceptional Raman spectroscopy enhancement. Through capturing and analyzing in situ Raman spectroscopy evidences on *OH, metal-O species and *CO evolution under 0.
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