An organocatalyst bound α-aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions.

Org Biomol Chem

Organic Chemistry Division, CSIR-National Chemical Laboratory, Pune-411008, India.

Published: July 2018

A catalyst bound α-aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.

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http://dx.doi.org/10.1039/c8ob01032cDOI Listing

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