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An intermolecular oxidative dearomatization of β-naphthols with N-hydroxycarbamates promoted by visible light was realized by means of photogenerated β-naphthol radical cation intermediates. With a commercially available organic dye, the naphthalenones bearing a fully substituted stereogenic center were obtained with up to 92 % yield under aerobic conditions (26 examples). In addition, the rearrangement of C-O coupling products to C-N coupling compounds could be achieved merely in the presence of Cs CO . This transformation simultaneously provides an attractive and synthetically useful approach to access the aminative dearomatization compounds.
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