The observation of perpendicular magnetic anisotropy (PMA) at MgO/Fe interfaces boosted the development of spintronic devices based on ultrathin ferromagnetic layers. Yet, magnetization reversal in the standard magnetic tunnel junctions (MTJs) with competing PMA and in-plane anisotropies remains unclear. Here we report on the field induced nonvolatile broken symmetry magnetization reorientation transition from the in-plane to the perpendicular (out of plane) state at temperatures below 50 K. The samples were 10 nm thick Fe in MgO/Fe(100)/MgO as stacking components of V/MgO/Fe/MgO/Fe/Co double barrier MTJs with an area of 20 × 20 μm. Micromagnetic simulations with PMA and different second order anisotropies at the opposite Fe/MgO interfaces qualitatively reproduce the observed broken symmetry spin reorientation transition. Our findings open the possibilities to develop multistate epitaxial spintronics based on competing magnetic anisotropies.
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http://dx.doi.org/10.1038/s41598-018-27720-7 | DOI Listing |
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January 2025
Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal, 462 066, India.
The structural and electronic changes are investigated in a 3D hybrid perovskite, methylhydrazinium lead chloride (MHyPbCl) from a host/guest perspective as it transitions from a highly polar to less polar phase upon cooling, using first-principles calculations. The two phases vary structurally in the guest (MHy) orientation and the two differently distorted host (lead halide) layers. These findings highlight the critical role of guest reorientation in reducing host distortion at high temperatures, making the former the primary order parameter for the transition, a notable contrast to the case of other hybrid perovskites.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Department of Physics, University of Kerala, Karyavattom 695581, Thiruvananthapuram, Kerala, India.
The effects of Na doping on the structure magnetic, electric, and magnetoelectric properties of GaFeOwere studied. Rietveld refinement of the XRD data reveals the formation of a single-phase trigonal structure with no impurity on Na doping up to 50% and a significant increase in lattice strain with doping. FTIR and Raman analysis further supported the phase purity of the samples.
View Article and Find Full Text PDFInorg Chem
January 2025
High Pressure & Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai, Trombay 400085, India.
Determining the dissociation mechanism of perchlorate materials remains a top priority to address sustainability, handling, processing, and synthesis issues of new and existing high-energy density materials vital to many industrial processes. We determined the dissociation mechanism of diglycine perchlorate (DGPCl) using vibrational spectroscopy, which unveiled the formation of ammonium perchlorate (AP) and carbon at high temperatures. Our studies establish that DGPCl shows multiple phase transitions upon heating.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110016, India.
We report the detailed investigation of the magnetic, transport, and magnetocaloric effects (MCEs) of GdSbSe by magnetic susceptibilityχ(T), isothermal magnetization(), resistivityρ(T,H), and heat capacityCp(T)measurements, crystallizing in the ZrSiS-type tetragonal crystal system with space group P4/nmm. Temperature-dependent magnetic susceptibility measurements revealed long-range antiferromagnetic ordering with two additional magnetic anomalies below Néel temperature (TN≈8.6K), corroborated through magnetocaloric and specific heat studies.
View Article and Find Full Text PDFACS Appl Polym Mater
December 2024
IMEM-BRT Group, Departament d'Enginyeria Química, EEBE, Universitat Politécnica de Catalunya, C/Eduard Maristany, 10-14, 08019 Barcelona, Spain.
The transition from insulator to electro-responsive has been successfully achieved by earlier studies for some inorganic materials by applying external stimuli that modify their 3D and/or electronic structures. In the case of insulating polymers, this transition is frequently accomplished by mixing them with other electroactive materials, even though a few physical treatments that induce suitable chemical modifications have also been reported. In this work, a smart approach based on the application of an electro-thermal reorientation process followed by a charged gas activation treatment has been developed for transforming insulating 3D printed polymers into electro-responsive materials.
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