The use of gas cluster media as a target for an intense femtosecond laser pulses is considered to be uniquely convenient approach for the development of a compact versatile pulsed source of ionizing radiation. Also, one may consider cluster media as a nanolab to investigate fundamental issues of intense optical fields interaction with sub-wavelength scale structures. However, conventional diagnostic methods fail to register highly charged ion states from a cluster plasma because of strong recombination in the ambient gas. In the paper we introduce high-resolution X-ray spectroscopy method allowing to study energy spectra of highly charged ions created in the area of most intense laser radiation. The emission of CO clusters were analyzed in experiments with 60 fs 780 nm laser pulses of 10 W/cm intensity. Theory and according X-ray spectra modeling allows to reveal the energy spectra and yield of highly charged oxygen ions. It was found that while the laser of fundamental frequency creates commonly expected monotonic ion energy spectrum, frequency doubled laser radiation initiates energy spectra featuring of distinctive quasi-monoenergetic peaks. The later would provide definite advantage in further development of laser-plasma based compact ion accelerators.
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http://dx.doi.org/10.1038/s41598-018-27665-x | DOI Listing |
Nat Commun
December 2024
Department of Physics and Astronomy, University of Calgary, 2500 University Drive N.W., Calgary, T2N 1N4, AB, Canada.
Patterns of ionospheric luminosity provide a unique window into our complex, coupled space environment. The aurora, for example, indicates plasma processes occurring thousands of km away, depositing immense amounts of energy into our polar ionospheres. Here we show observations of structured continuum emission associated with the dynamic aurora.
View Article and Find Full Text PDFRev Sci Instrum
December 2024
X-ray Astrophysics Laboratory, NASA Goddard Space Flight Center, Greenbelt, Maryland 20771, USA.
This paper presents progress made toward the overarching goal to adapt single-photon-counting microcalorimeters to magnetic fusion energy research and demonstrate the value of such measurements for fusion. Microcalorimeter spectrometers combine the best characteristics of x-ray instrumentation currently available on fusion devices: high spectral resolution similar to an x-ray crystal spectrometer and broad spectral coverage sufficient to measure impurity species from Be to W. As a proof-of-principle experiment, a NASA-built x-ray microcalorimeter spectrometer has been installed on the Madison Symmetric Torus (MST) at the Wisconsin Plasma Physics Laboratory.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing 210037, People's Republic of China. Electronic address:
For the typical ESIPT process, the proton transfer process is often completed via the intramolecular hydrogen bond (IHB) with oxygen or nitrogen as proton donor or proton acceptor. In recent years, the ESIPT process for sulfur-containing hydrogen bonds has received more and more attention, but it has been rarely reported. We systematically studied the ESIPT processes and photophysical properties of 2-(benzothiophene-2-yl)-3-hydroxy-4H-chromen-4-one (BTOH), 2-(benzothiophene-2-yl)-3-mercapto-4H-chromen-4-one (BTSH) and 2-(benzothiophen-2-yl)-3-hydroxy-4H-chromene-4-thione (BTS) at the HISSbPBE/6-31+G(d,p) and TD-HISSbPBE/6-31+G(d,p) computational level.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Physics, RTM Nagpur University, Nagpur 440033, India.
While searching for a new host suitable for near infrared (NIR) emission, we explored a new composition NaLaMgWO. The samples were prepared by solid state reaction method. X-ray Diffraction confirms crystallization of NaLaMgWO in monoclinic system.
View Article and Find Full Text PDFRapid Commun Mass Spectrom
March 2025
Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Canada.
Rationale: In electrospray ionization and atmospheric pressure chemical ionization, the protonation site directly guides the ion's dissociation. But what if the site of protonation is ambiguous? In this study, we explored the unimolecular reactions of protonated α- and β-pinene ions with a combination of tandem mass spectrometry and theory. Each has multiple potential protonation sites that influence their chemistry.
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