In this study, a new method was reported for the fabrication of the nanostructured CuO/Al thermite film on a Cu substrate. The CuO nanorod (NR) arrays grew vertically from the Cu surfaces by electrochemical anodization processes, followed by the deposition of an Al layer on the CuO NRs via magnetron sputtering to form a core/shell CuO/Al nanothermite film, whose component, structure and morphology were subsequently characterized. In addition, the energy-release characteristics of the obtained nanothermite film were investigated using thermal analyses and laser ignition tests. All evidence demonstrates that the obtained CuO/Al is of a uniform structure and has superb energy performance. Impressively, the resulting material is potentially useful in applications of functional energetic chips due to its easy integration with microelectromechanical systems (MEMS) technologies.
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http://dx.doi.org/10.1088/1361-6528/aacc57 | DOI Listing |
Langmuir
November 2020
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China.
The interface layer is responsible for the outward migration of oxygen atoms, which subsequently leads to an adjustment in the energetic performance of nanothermite films. In this study, sandwich-structured CuO@Ni/Al and CuO@NiO/Al nanowire thermite films were successfully prepared to investigate the effects of the interface layer on the heat-release, ignition, and combustion performance. The effects of the Ni and NiO interface layers are extremely different on the heat-release performance and combustion properties of the CuO/Al nanowire thermite film.
View Article and Find Full Text PDFNanotechnology
January 2020
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, People's Republic of China.
CuO@Al nanothermites with Al shell and CuO core were successfully fabricated via a simple self-assembly route. The composition and morphology of CuO@Al nanothermites were analyzed by x-ray diffraction and field-emission scanning electron microscopy in detail. When the equivalence ratio was 1.
View Article and Find Full Text PDFNanotechnology
September 2018
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, People's Republic of China.
In this study, a new method was reported for the fabrication of the nanostructured CuO/Al thermite film on a Cu substrate. The CuO nanorod (NR) arrays grew vertically from the Cu surfaces by electrochemical anodization processes, followed by the deposition of an Al layer on the CuO NRs via magnetron sputtering to form a core/shell CuO/Al nanothermite film, whose component, structure and morphology were subsequently characterized. In addition, the energy-release characteristics of the obtained nanothermite film were investigated using thermal analyses and laser ignition tests.
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