Cationic nickel(ii) complexes of two ring-contracted porphyrinoid ligands distantly related to the corrins were prepared by metal templated macrocyclisation. The compounds show reversible electron transfer processes and were found to be the first porphyrinoid-based catalysts for C-C cross-coupling.
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| http://dx.doi.org/10.1039/c5sc03663a | DOI Listing |
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