Selective Methylation of Arenes: A Radical C-H Functionalization/Cross-Coupling Sequence.

Angew Chem Int Ed Engl

Department Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany.

Published: August 2018

A selective, nonchelation-assisted methylation of arenes has been developed. The overall transformation, which combines a C-H functionalization reaction with a nickel-catalyzed cross-coupling, offers rapid access to methylated arenes with high para selectivity. The reaction is amenable to late-stage methylation of small-molecule pharmaceuticals.

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http://dx.doi.org/10.1002/anie.201804628DOI Listing

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