Refocused linewidths less than 10 Hz in H solid-state NMR.

J Magn Reson

Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne 1015, Switzerland. Electronic address:

Published: August 2018

Coherence lifetimes in homonuclear dipolar decoupled H solid-state NMR experiments are usually on the order of a few ms. We discover an oscillation that limits the lifetime of the coherences by recording spin-echo dephasing curves. We find that this oscillation can be removed by the application of a double spin-echo experiment, leading to coherence lifetimes of more than 45 ms in adamantane and more that 22 ms in β-AspAla, corresponding to refocused linewidths of less than 7 and 14 Hz respectively.

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http://dx.doi.org/10.1016/j.jmr.2018.06.001DOI Listing

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