The kinetic compensation effect in the logistic distributed activation energy model (DAEM) for lignocellulosic biomass pyrolysis was investigated. The sum of square error (SSE) surface tool was used to analyze two theoretically simulated logistic DAEM processes for cellulose and xylan pyrolysis. The logistic DAEM coupled with the pattern search method for parameter estimation was used to analyze the experimental data of cellulose pyrolysis. The results showed that many parameter sets of the logistic DAEM could fit the data at different heating rates very well for both simulated and experimental processes, and a perfect linear relationship between the logarithm of the frequency factor and the mean value of the activation energy distribution was found. The parameters of the logistic DAEM can be estimated by coupling the optimization method and isoconversional kinetic methods. The results would be helpful for chemical kinetic analysis using DAEM.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.biortech.2018.05.092 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis.
Bioresour Technol
October 2018
Biomass Energy Engineering Research Center, Key Laboratory of Urban Agriculture (South) Ministry of Agriculture, School of Agriculture and Biology, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, People's Republic of China; CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, People's Republic of China. Electronic address: http://biofuels.sjtu.edu.cn.
The kinetic compensation effect in the logistic distributed activation energy model (DAEM) for lignocellulosic biomass pyrolysis was investigated. The sum of square error (SSE) surface tool was used to analyze two theoretically simulated logistic DAEM processes for cellulose and xylan pyrolysis. The logistic DAEM coupled with the pattern search method for parameter estimation was used to analyze the experimental data of cellulose pyrolysis.
View Article and Find Full Text PDFHow Interdisciplinary Teamwork Contributes to Psychosocial Cancer Support.
Cancer Nurs
March 2020
Author Affiliations: Department of Oncology, Ghent University Hospital (Mr Daem, Mr Schrauwen, and Ms Leroux); and Department of Public Health, University Centre for Nursing and Midwifery, Ghent University (Drs Verbrugghe, Van Hecke, and Grypdonck), Belgium.
Background: The organization of psychosocial care is rather complex, and its provision diverse. Access is affected by the acceptance and attitude of patients and professional caregivers toward psychosocial care.
Objectives: The aims of this study were to examine when patients with cancer experience quality psychosocial care and to identify circumstances in collaboration that contribute to patient-perceived positive psychosocial care.
Studies on thermokinetic of Chlorella pyrenoidosa devolatilization via different models.
Bioresour Technol
November 2017
School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, China. Electronic address:
The thermokinetics of Chlorella pyrenoidosa (CP) devolatilization were investigated based on iso-conversional model and different distributed activation energy models (DAEM). Iso-conversional process result showed that CP devolatilization roughly followed a single-step with mechanism function of f(α)=(1-α), and kinetic parameters pair of E=180.5kJ/mol and A=1.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!