Probing heterogeneity of NIR induced secondary fluorescence from DNA-stabilized silver nanoclusters at the single molecule level.

Phys Chem Chem Phys

Nanoscience Center and Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark.

Published: June 2018

In this communication, we investigate optically activated delayed fluorescence (OADF) from DNA-stabilized silver nanoclusters (DNA-AgNCs) at the single molecule level, and we probe the heterogeneity in the primary fluorescence (PF) intensity, NIR induced secondary fluorescence (SF) intensity and SF/PF ratio. Our experiments reveal a heterogeneous distribution in the SF/PF ratio, indicating that engineering of DNA-AgNCs towards a high SF/PF ratio and high OADF signal for background-free imaging might be possible.

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http://dx.doi.org/10.1039/c8cp02584cDOI Listing

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