Materials combining high porosity, mechanical durability, and multifunctionality have drawn significant research interest because of their potential in engineering applications. Herein, the porous air-dried nanocomposite aerogels containing reduced graphene oxide (RGO) and chitosan (CS) are fabricated by self-assembling an aqueous dispersion of graphene oxide and chitosan with the addition of hydroiodic acid (HI) followed by recasting the hybrid hydrogel with an ice-template method. The strong cross-linked composite aerogels obtained have reversible compressibility, exceptional elasticity, and high electrical conductivity, which are derived from the restacking inhibition and steric hindrance of the polymer chains. What's more, the successive soaking-drying experiments indicate that the as-prepared graphene-based aerogels exhibit excellent environmental stability and reuseability. The regenerated electrical conductivity remains almost the same and more than 90% of its maximum compressive stress at a strain of up to 92% is retained after five cycles. This makes them ideal candidates for potential applications in areas of supercapacitors and energy storage.
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http://dx.doi.org/10.1021/acsami.8b04689 | DOI Listing |
Planta
January 2025
Department of Biotechnology, Manipal School of Life Sciences, Manipal Academy of Higher Education, Manipal, India.
Optimizing environmental factors can significantly increase the growth and secondary metabolite synthesis of hydroponically grown medicinal plants. This approach can help increase the quality and quantity of pharmacologically important metabolites to enhance therapeutic needs. Medicinal plants are key therapeutic sources for treating various ailments.
View Article and Find Full Text PDFNanoscale
January 2025
Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing, 401331, PR China.
The development of environmentally friendly, high-efficiency, stable, earth-abundant and non-precious metal-based electrocatalysts with fast kinetics and low overpotential for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is of exceeding significance but still challenging. Herein, a bifunctional electrode of unique hierarchical NiFe-LDH/Ni/NiCoS/NF (NiFe-LDH = nickel-iron layered double hydroxide and NF = nickel foam) electrocatalytic architecture, which is built up from NiFe-LDH nanosheets, Ni nanoparticles and NiCoS nanoneedles sequentially arrayed on a porous NF substrate, has been prepared by a facile hydrothermal and electrodeposition method. This electrocatalytic architecture is binder-free and its outer NiFe-LDH nanosheets can effectively prevent the oxidation of inner Ni nanoparticles and corrosion of NiCoS nanoneedles during water electrolysis.
View Article and Find Full Text PDFJ Water Health
January 2025
Marwadi University Research Center, Department of Microbiology, Faculty of Sciences, Rajkot 360003, Gujrat, India.
The pollution index is a helpful tool for assessing the quality of groundwater. To assess the water quality in the southern segment of Barmer District (Rajasthan), India, we collected 20 samples of groundwater from the post-monsoon 2021 and pre-monsoon 2022 periods. Physicochemical parameters such as pH, electrical conductivity (EC), total hardness, Cl, SO, F, NO, total dissolved solids, Ca, and Mg were analyzed.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Materials Research and Engineering, Agency for Science Technology and Research, 2 Fusionopolis Way, 08-03 Innovis, Singapore 138634, Singapore.
Thermoelectric properties of conducting polymers typically suffer from molecular chain disordering, as charge transport is predominantly controlled by morphology. This is especially more problematic when counterions are introduced to tune the carrier concentration for optimal thermoelectric performance, which disturbs the morphology further. In this work, we introduce a new avenue for enhancing thermoelectric properties without needing to regulate the morphology, namely, by controlling the coulombic interaction between polarons and counterions.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Nanotech@surfaces Laboratory, Empa - Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland.
Polyacene analogues, consisting of short acene segments separated by nonbenzenoid rings, offer intriguing electronic properties and magnetic interactions. Pentalene-bridged polyacenes (PPs), in particular, hold promise for enhancing the electrical conductivity and potential open-shell ground states. However, PPs have remained elusive in solution chemistry due to poor solubility and limited synthetic protocols.
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