Tb, Eu Co-doped CsPbBr QDs Glass with Highly Stable and Luminous Adjustable for White LEDs.

ACS Appl Mater Interfaces

College of Chemistry and Materials Engineering, College of Life and Environmental Science , Wenzhou University, Wenzhou 325035 , People's Republic of China.

Published: June 2018

AI Article Synopsis

  • Researchers have incorporated rare-earth cations, terbium (Tb) and europium (Eu), into cesium lead bromide (CsPbBr) quantum dot glass using a melt-quenching method, enhancing its luminescent properties.
  • Tb emits green light which slightly shifts the emission peak due to energy transfer with CsPbBr, while Eu emits red light to address red deficiency in the material.
  • The co-doping of Tb and Eu enables the production of high-performance white light-emitting diodes with a color-rendering index of 85.7 and luminous efficiency of 63.21 lm/W, showcasing the potential for these materials as effective warm light sources.

Article Abstract

Herein, we have introduced rare-earth cations Tb and Eu into CsPbBr QDs glass by conventional melt-quenching. Rare-earth cations like Tb emit green light, causing the main peak of bromide lead cesium to exhibit some redshift, owing to the energy transfer between CsPbBr and Tb. To achieve adjustable light, Eu emits red light, which was doped in this glass with different proportions to solve the problem of red deficiency. More importantly, Tb and Eu co-doped CsPbBr QDs glass shows a series of desirable characteristics due to the energy transfer between Tb and Eu. Interestingly, the blue light radiated by blue chip can excite Tb, Eu, and CsPbBr perovskite effectively. We acquired high-performance white light-emitting diodes with color-rendering index, color coordinate transformation, and luminous efficiency of 85.7, 4945 K, and 63.21 lm/W under the current of 20 mA. This acquired Tb, Eu co-doped CsPbBr QDs glass proved the significant feasibility of luminescent materials in solid warm light source.

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Source
http://dx.doi.org/10.1021/acsami.8b05003DOI Listing

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