Unlike graphene nanostructures, various physical properties of nanostructured MoS have remained unexplored due to the lack of established fabrication routes. Herein, we have reported unique electrostatic properties of MoS nanostructures, fabricated in a controlled manner of different geometries on 2D flake by using focused laser irradiation technique. Electrostatic force microscopy has been carried out on MoS nanostructures by varying tip bias voltage and lift height. The analysis depicts no contrast flip in phase image of the patterned nanostructure due to the absence of free surface charges. However, prominent change in phase shift at the patterned area is observed. Such contrast changes signify the capacitive interaction between tip and nanostructures at varying tip bias voltage and lift height, irrespective of their shape and size. Such unperturbed capacitive behavior of the MoS nanostructures offer modulation of capacitance in periodic array on 2D MoS flake for potential application in capacitive devices.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1088/1361-6528/aac9b2 | DOI Listing |
ACS Nano
January 2025
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
Controlling charge transport at the interfaces of nanostructures is crucial for their successful use in optoelectronic and solar energy applications. Mixed-dimensional heterostructures based on single-walled carbon nanotubes (SWCNTs) and transition metal dichalcogenides (TMDCs) have demonstrated exceptionally long-lived charge-separated states. However, the factors that control the charge transport at these interfaces remain unclear.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Physics, Memory and Catalyst Research Center, Hankuk University of Foreign Studies, Yongin, 17035, Republic of Korea.
MoO is a promising transition metal oxide due to its high dielectric constant (κ) and multifunctionality in electronic and optoelectronic applications. Oxidation-induced nanoscale MoO, synthesized via oxidation scanning probe lithography (o-SPL) of MoS, requires in-depth characterization of its dielectric properties. In this study, we measured the κ of a single MoO nanostructure, which was confirmed to be in the amorphous phase through water solubility tests and high-resolution transmission electron microscopy (HRTEM).
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Key Laboratory of Optic-Electric Sensing and Analytical Chemistry for Life Science, MOE, Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China. Electronic address:
The accurate and reliable quantification of the levels of disease markers in human sweat is of significance for health monitoring through wearable sensing technology, but the sensors performed in real sweat always suffer from biofouling that cause performance degradation or even malfunction. We herein developed a wearable antifouling electrochemical sensor based on a novel multifunctional hydrogel for the detection of targets in sweat. The integration of polyethylene glycol (PEG) into the sulfobetaine methacrylate (SBMA) hydrogel results in a robust network structure characterized by abundant hydrophilic groups on its surface, significantly enhancing the PEG-SBMA hydrogel's antifouling and mechanical properties.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Chemistry and Biochemistry, Queens College, Flushing, New York 11367, United States.
Semiconductor nanomaterials and nanostructured interfaces have important technological applications, ranging from fuel production to electrosynthesis. Their photocatalytic activity is known to be highly heterogeneous, both in an ensemble of nanomaterials and within a single entity. Photoelectrochemical imaging techniques are potentially useful for high-resolution mapping of photo(electro)catalytic active sites; however, the nanoscale spatial resolution required for such experiments has not yet been attained.
View Article and Find Full Text PDFACS Nano
January 2025
Instituto de Física de São Carlos, Universidade de São Paulo, São Carlos 13566-590, Brazil.
Monolayers of transition-metal dichalcogenides, such as MoS, have attracted significant attention for their exceptional electronic and optical properties, positioning them as ideal candidates for advanced optoelectronic applications. Despite their strong excitonic effects, the atomic-scale thickness of these materials limits their light absorption efficiency, necessitating innovative strategies to enhance light-matter interactions. Plasmonic nanostructures offer a promising solution to overcome those challenges by amplifying the electromagnetic field and also introducing other mechanisms, such as hot electron injection.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!