Crystal structure of tri-benzyl-bis-(tetra-hydro-furan-κ)lutetium(III).

Acta Crystallogr E Crystallogr Commun

Department of Chemistry, University of Alberta, Edmonton, AB T6G 2G2, Canada.

Published: February 2018

In the title compound, [Lu(CH)(CHO)] (), the Lu ion is coordinated by three benzyl and two tetra-hydro-furan ligands. Two of the benzyl groups are bonded in a classical η-fashion through the methyl-ene the -carbon atom of the benzyl ligand in addition to bonding through the methyl-ene C atom, resulting in a modified trigonal-bipyramidal coordination geometry about the Lu center.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956313PMC
http://dx.doi.org/10.1107/S2056989017018254DOI Listing

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