A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)CHN)(CO)(2-S-CHN)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand.
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| http://dx.doi.org/10.1021/acs.inorgchem.8b00838 | DOI Listing |
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