In this work, a method for the measurement of surface tension using continuous periodic forcing is presented. To reduce gravitational effects, samples are electrostatically levitated prior to forcing. The method, called Faraday forcing, is particularly well suited for fluids that require high temperature measurements such as liquid metals where conventional surface tension measurement methods are not possible. It offers distinct advantages over the conventional pulse-decay analysis method when the sample viscosity is high or the levitation feedback control system is noisy. In the current method, levitated drops are continuously translated about a mean position at a small, constant forcing amplitude over a range of frequencies. At a particular frequency in this range, the drop suddenly enters a state of resonance, which is confirmed by large executions of prolate/oblate deformations about the mean spherical shape. The arrival at this resonant condition is a signature that the parametric forcing frequency is equal to the drop's natural frequency, the latter being a known function of surface tension. A description of the experimental procedure is presented. A proof of concept is given using pure Zr and a TiZrNi alloy as examples. The results compare favorably with accepted literature values obtained using the pulse-decay method.
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http://dx.doi.org/10.1038/s41526-018-0044-1 | DOI Listing |
ACS Nano
January 2025
Department of Chemical Engineering, Waterloo Institute for Nanotechnology, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1, Canada.
A surfactant is an efficient and common additive used to enhance the spreading of droplets on hydrophobic surfaces. However, a high surfactant concentration is required to achieve the desired performance, resulting in environmental pollution and increased costs. Additionally, the pesticide loading capacity of surfactants at low concentrations (below their critical micelle concentrations) is a concern.
View Article and Find Full Text PDFIn this Letter, we show the attraction of a microbubble at a fiber end face by the solute Marangoni force. The microbubble is formed by partial filling of an ethanol-water mixture in the microcavity that is spliced to the end face of a single-mode fiber. Due to different surface tension of ethanol and water, the uneven temperature gradient induced by a laser causes the non-uniform distribution of ethanol-water molecules on the bubble surface.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemical Engineering and Environmental Technology, Universidad de Zaragoza, Campus Río Ebro-Edificio I+D, 50018 Zaragoza, Spain.
The emergence of green chemistry and engineering principles to enforce sustainability aspects has ensured the prevalence of green solvents and green processes. Our study addresses this quest by exploring drug delivery applications of hydrophobic deep eutectic solvents (DESs) which are alternative green solvents. Initially, this work showcases the hydrophobic drug solubilization capabilities of a natural hydrophobic DES, menthol, and decanoic acid.
View Article and Find Full Text PDFLangmuir
January 2025
School of Chemical Engineering, Department of Chemistry and Materials Science, Aalto University, Tietotie 3 Espoo 02150, Finland.
Superhydrophobic surfaces find applications in numerous biomedical scenarios, requiring the repellence of biofluids and biomolecules. Plastron, the trapped air between a superhydrophobic surface and a wetting liquid, plays a pivotal role in biofluid repellency. A key challenge, however, is the often short-lived plastron stability in biofluids and the lack of knowledge surrounding it.
View Article and Find Full Text PDFEnviron Technol
January 2025
Department of Civil Engineering, The University of Hong Kong, Hong Kong SAR, People's Republic of China.
The remediation of oil-contaminated soil poses significant environmental challenges, often necessitating innovative approaches for effective and sustainable solutions. This study focuses on the synthesis, characterisation, and application of biodegradable capsules loaded with surfactant for enhanced oil remediation of a clean sand. By controlling the release properties of capsules, the research aims to overcome the limitations of conventional surfactant-based remediation methods, such as rapid washout and reduced efficacy over time.
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