Organic molecules of DIDB can inherently assemble into fluorescent green-emissive microwires with a low photoluminescence quantum efficiency (PLQY) of 1.0%. Impressively, by doping DIDB into the nonluminous 4-iodobenzonitrile crystal matrix with a molar ratio of 1 : 100, phosphorescent yellow-emissive microwires with a much higher PLQY of 50.5% are obtained.
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Fluorescence/phosphorescence-conversion in self-assembled organic microcrystals.
Chem Commun (Camb)
June 2018
Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 215123, China.
Organic molecules of DIDB can inherently assemble into fluorescent green-emissive microwires with a low photoluminescence quantum efficiency (PLQY) of 1.0%. Impressively, by doping DIDB into the nonluminous 4-iodobenzonitrile crystal matrix with a molar ratio of 1 : 100, phosphorescent yellow-emissive microwires with a much higher PLQY of 50.
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