A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes.

Chem Commun (Camb)

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China.

Published: May 2018

Homo (Au3)- and heterotrinuclear coinage metal complexes (Au2Ag and Au2Cu) ligated by the first tritopic carbanionic N-heterocyclic carbene (NHC) have been prepared by deprotonation of ditopic NHC digold complexes and structurally characterized by single-crystal X-ray diffraction.

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Source
http://dx.doi.org/10.1039/c8cc02192aDOI Listing

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