We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either calix[6]arene (Calix6) or calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim of Calix6 or Calix8. An adaptive nature of the heteromacrocyclic assembly towards the binding of a model guest has been observed.

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http://dx.doi.org/10.1039/c8cc03415jDOI Listing

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