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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand. | LitMetric
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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand.

Masaichi Saito Naoki Matsunaga Jumpei Hamada Shunsuke Furukawa Mao Minoura Susann Wegner Juri Barthel Christoph Janiak

Dalton Trans

Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama, 338-8570, Japan.

Published: July 2018

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru-Rh complex exhibits an electronic property different from those of the corresponding Ru-Ru and Rh-Rh complexes. The Ru-Rh complex can be decomposed in ionic liquids to metal nanoparticles.

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http://dx.doi.org/10.1039/c8dt01455hDOI Listing

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