Graphdiyne (GDY), a novel two-dimensional full-carbon material, has attracted lots of attention because of its high conjugated system comprising sp and sp-hybridized carbons. The distinctive structure characteristics endow it unique electronic structure, uniform distributed pores and excellent chemical stability. A novel GDY-supported NiFe layered double hydroxide (LDH) composite was successfully prepared for the first time. By taking advantage of the increased surface active areas and improved conductivity, the designed hierarchical GDY@NiFe composite exhibits outstanding catalytic activity that only required a small overpotential about 260 mV to achieve the current density of 10 mA cm. The nanocomposite shows excellent durability in alkaline medium implying a superior OER electrocatalytic activity. It is anticipated that the as-prepared GDY@NiFe composite electrocatalyst provide new insights in designing graphdiyne-supported electrocatalyst materials for oxygen evolution application.
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http://dx.doi.org/10.1021/acsami.8b03345 | DOI Listing |
Clin Oral Implants Res
January 2025
Etiology and Therapy of Periodontal and Periimplant Diseases (ETEP) Research Group, Faculty of Dentistry, Complutense University, Madrid, Spain.
Aim: To evaluate in vitro the antibacterial efficacy and cytocompatibility of different implant-decontamination methods, using both 2D and 3D peri-implant mucosa models.
Methods: Four decontamination methods [chlorhexidine (CHX), electrolytic treatment (GS), curcumin (CUR), xanthohumol (XN)] were compared in four independent experiments, three with a 2D peri-implant mucosa model on titanium surfaces and another on a 3D peri-implant mucosa model. These decontamination procedures were tested for their antibacterial effect using a multispecies biofilm model with Streptococcus oralis, Actinomyces naeslundii, Veillonella dispar, and Porphyromonas gingivalis for 24 h.
Inorg Chem
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, Shandong 250014, China.
Seawater electrolysis has emerged as a promising approach for the generation of hydrogen energy, but the production of deleterious chlorine derivatives (e.g., chloride and hypochlorite) presents a significant challenge due to the severe corrosion at the anode.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, China.
Solar-driven photocatalytic water splitting offers a sustainable pathway to produce green hydrogen, yet its practical application encounters several challenges including inefficient photocatalysts, sluggish water oxidation, severe reverse reactions and the necessity of separating produced hydrogen and oxygen gases. Herein, we design and develop a photocatalytic system composed of two separate reaction parts: a hydrogen evolution cell containing halide perovskite photocatalysts (MoSe-loaded CH(NH)PbBrI) and an oxygen evolution cell containing NiFe-layered double hydroxide modified BiVO photocatalysts. These components are bridged by a I/I redox couple to facilitate electron transfer, realizing efficient overall water splitting with a solar-to-hydrogen conversion efficiency of 2.
View Article and Find Full Text PDFSmall
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, Shandong, 250014, China.
Renewable energy-powered seawater electrolysis is a green and attractive technique for producing high-purity hydrogen. However, severe chlorideions (Cl) and their derivatives tend to corrode anodic catalysts at ampere-level current densities and hinder the application of seawater-to-H systems. Herein, a polycalmagite (PCM)-coated NiFe layered double hydroxide is presented on Ni foam (NiFe LDH@PCM/NF) that exhibits exceptional stability in alkaline seawater.
View Article and Find Full Text PDFJ Colloid Interface Sci
April 2025
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014 Shandong, China; Center for High Altitude Medicine, West China Hospital, Sichuan University, Chengdu 610041 Sichuan, China. Electronic address:
Seawater splitting is increasingly recognized as a promising technique for hydrogen production, while the lack of good electrocatalysts and detrimental chlorine chemistry may hinder further development of this technology. Here, the interfacial engineering of manganese dioxide nanoparticles decorated on NiFe layered double hydroxide supported on nickel foam (MnO@NiFe LDH/NF) is reported, which works as a robust catalyst for alkaline seawater oxidation. Density functional theory calculations and experiment findings reveal that MnO@NiFe LDH/NF can selectively enrich OH and repel Cl in oxygen evolution reaction (OER).
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