Two Cu complexes of 3,4,5-tri-methyl-1-pyrazole.

The crystal structure of complexes of 3,4,5-tri-methyl-1-pyrazole with CuCl·2HO and Cu(NO)·2.5HO are presented, namely di-μ-chlorido-bis[chloridobis(3,4,5-trimethyl-1-pyrazole-κ)copper(II)], [CuCl(CHN)] () and aquatetrakis(3,4,5-trimethyl-1-pyrazole-κ)copper(II) dinitrate, [Cu(CHN)(HO)](NO) (), and compared to the previously determined structures for 3-methyl-1-pyrazole and 3,5-di-methyl-1-pyrazole. CuCl forms a 2:1 ligand-to-metal chloride-bridged complex with 3,4,5-tri-methyl-1-pyrazole, with a square-pyramidal coordination geometry about each copper(II) center. Similarly to the previously obtained 3,5-di-methyl-1-pyrazole complex with CuCl, the pyrazole ligands are to each other, with two chloride ions bridging the two copper(II) centers, and a terminal chloride ion occupying the axial position. Cu(NO) forms a 4:1 ligand-to-metal complex with 3,4,5-tri-methyl-1-pyrazole that is also arranged in a square-pyramidal geometry about Cu. The newly obtained copper(II) complex has the same coordination geometry as the 3,5-di-methyl-1-pyrazole complex, including an axial water mol-ecule, two nitrate ions hydrogen-bonded to the water mol-ecule, and four pyrazole ligands in the equatorial plane, suggesting that similar steric forces are at play in the formation of these complexes.