The elastic backbone is the set of all shortest paths. We found a new phase transition at p_{eb} above the classical percolation threshold at which the elastic backbone becomes dense. At this transition in 2D, its fractal dimension is 1.750±0.003, and one obtains a novel set of critical exponents β_{eb}=0.50±0.02, γ_{eb}=1.97±0.05, and ν_{eb}=2.00±0.02, fulfilling consistent critical scaling laws. Interestingly, however, the hyperscaling relation is violated. Using Binder's cumulant, we determine, with high precision, the critical probabilities p_{eb} for the triangular and tilted square lattice for site and bond percolation. This transition describes a sudden rigidification as a function of density when stretching a damaged tissue.
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http://dx.doi.org/10.1103/PhysRevLett.120.175701 | DOI Listing |
Polymers (Basel)
December 2024
Department of Chemical Engineering, Hanyang University, Ansan 15588, Republic of Korea.
Conventional PP with a linear chain structure is not suitable for foam processing due to its poor rheological properties. In this study, PP was modified with PE through reactive melt blending of maleic anhydride-grafted PP (MA-PP) with a small amount of PE bearing glycidyl groups on its backbone (G-PE), with the aim of enhancing the melt rheological properties of PP to make it suitable for foam processing. An anhydride-epoxy reaction occurred between MA-PP and G-PE during the melt processing, resulting in the formation of a crosslinked polymer network, which was confirmed by FTIR spectroscopy, a solubility test, and the presence of a rubbery plateau above the melting point.
View Article and Find Full Text PDFJ Chem Phys
December 2024
Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109, USA.
Organic-inorganic hybrid materials are explored for application as solid electrolytes for lithium-ion batteries. The material consists of a porous silica network, of which the pores are infiltrated by poly(ethylene oxide) and lithium perchlorate. The synthesis involves two steps: First, the inorganic backbone is created by the acid-catalyzed sol-gel synthesis of tetraethyl orthosilicate to ensure continuity of the backbone in three dimensions.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Key Laboratory of Bioactive Materials, Ministry of Education, College of Life Sciences, Nankai University, Tianjin 300071, China. Electronic address:
The development of self-elastic sponges with enhanced hemostatic and antibacterial properties to treat noncompressible hemorrhage and facilitate wound healing remains challenging. Herein, we prepared a chitosan sponge reinforced with lauric acid-modified quaternized chitosan (LQC) and attapulgite, features a porous structure, high self-elasticity, and rapid shape recovery. The incorporation of LQC conferred the sponge with an enhanced capacity to promote the adhesion, aggregation, and activation of blood cells, and resistance to infection by Staphylococcus aureus, Escherichia coli, and Methicillin-resistant Staphylococcus aureus; the incorporation of attapulgite enhanced the hydrophilicity and mechanical strength of the sponge, and its ability to activate the intrinsic and extrinsic coagulation pathways.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Materials Science and Engineering, Binghamton University, Binghamton, New York 13905, United States.
Atomic layer deposition (ALD) is a popular method of coating battery electrodes with metal oxides for improved cycling stability. While significant research has focused on the interaction between the reactive metal alkyl precursor and the electrode materials, little is known about the reactivity of the precursor toward other components of the battery electrode, such as the polymer binder. This study presents a combined computational and experimental investigation of the reaction between the popular polyvinylidene (PVDF) binder and the trimethylaluminum (TMA) precursor commonly used for coating AlO by ALD.
View Article and Find Full Text PDFFront Bioeng Biotechnol
December 2024
Academy of Medical Engineering and Translational Medicine, Tianjin University, Tianjin, China.
Purpose: Spine is the most commonly found fracture site due to osteoporosis. Combined exercise including high-impact and resistance exercise shows the potential to improve bone mineral density (BMD) in the spine. However, the mechanical loading introduced by exercise, which is the mechanism of BMD changes, has not been investigated.
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