Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely , which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of 3 nm and orthogonal microporous channels of 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe(μ-O)(COO)] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5909329PMC
http://dx.doi.org/10.1039/c7sc04829gDOI Listing

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