Here, we fabricated an oxygen-deficient WO3-x crystalline/amorphous homojunction with a strong and tunable localized surface plasmon resonance (LSPR) absorption and realized selective solar modulation over infrared light by controlling the experimental parameters. The homojunction shows good LSPR stability in photochromic cycles, which paves the way to control LSPR applications.
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http://dx.doi.org/10.1039/c8cc02211a | DOI Listing |
Nanotechnology
October 2024
Institute for Quantum Computing, University of Waterloo, Waterloo N2L 3G1, Canada.
Fast and accurate detection of light in the near-infrared (NIR) spectral range plays a crucial role in modern society, from alleviating speed and capacity bottlenecks in optical communications to enhancing the control and safety of autonomous vehicles through NIR imaging systems. Several technological platforms are currently under investigation to improve NIR photodetection, aiming to surpass the performance of established III-V semiconductor p-i-n (PIN) junction technology. These platforms include-grown inorganic nanocrystals (NCs) and nanowire arrays, as well as hybrid organic-inorganic materials such as graphene-perovskite heterostructures.
View Article and Find Full Text PDFJ Colloid Interface Sci
July 2024
School of Chemical Engineering/Xi'an Key Laboratory of Special Energy Materials, Northwest University, Xi'an 710069, PR China; Shaanxi Key Laboratory for Carbon Neutral Technology, Xi'an 710069, PR China. Electronic address:
The enhancement of charge separation and utilization efficiency in both the bulk phase and interface of semiconductor photocatalysts, as well as the expansion of light absorption range, are crucial research topics in the field of photocatalysis. To address this issue, twinned CdZn5S (T-CZS) homojunctions consisting of wurtzite CdZnS (WZ-CZS) and zinc blende CdZnS (ZB-CZS) were synthesized via a hydrothermal method to facilitate the bulk-phase charge separation. Meanwhile, CuSe with localized surface plasmon resonance effect (LSPR) generated by Cu vacancies was also obtained through a hydrothermal process.
View Article and Find Full Text PDFTalanta
August 2023
College of Resources and Environment, Southwest University, Chongqing, 400715, China. Electronic address:
The development of new efficient contrast nanoprobe has been greatly concerned in the field of scattering imaging for sensitive and accurate detection of trace analytes. In this work, the non-stoichiometric CuSe nanoparticle with typical localized surface plasmon resonance (LSPR) properties originating from their copper deficiency as a plasmonic scattering imaging probe was developed for sensitive and selective detection of Hg under dark-field microscopy. Hg can compete with Cu(I)/Cu(II) which were sources of optically active holes coexisting in these CuSe nanoparticles for its higher affinity with Se.
View Article and Find Full Text PDFMaterials that exhibit photothermal effect have attracted enormous research interests due to their ability to strongly absorb light and effectively transform it into heat for a wide range of applications in biomedical, environmental and energy related fields. The past decade has witnessed significant advances in the preparation of a variety of photothermal materials, mainly due to the emergence of many nano-enabled new materials, such as plasmonic metals, stoichiometric/non-stoichiometric semiconductors, and the newly emerging MXenes. These photothermal nanomaterials can be hybridized with other constituents to form functional hybrids or composites for achieving enhanced photothermal performance.
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