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A molecular carousel, that is the appearance of the structure of the title compound [1⋅2 py], the first complex of a new structure type prepared by a highly selective condensation reaction from the equally new complex [Fe(C H GaMe ) ]. The first gallium bridged [m.m]ferrocenophane [{Fe(C H ) } {GaMe(C H N)} ] is formed as an intermediate; this compound can also be prepared in a planned synthesis and can be converted into [1⋅2 py] by warming. The complex [1⋅2 py] as well as [1⋅2 Et O] and [1⋅2 DMSO], which were formed by donor exchange, offers various interesting properties, for example, [1⋅2 DMSO] can be reversibly oxidized to the mono-, di-, and trication.

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http://dx.doi.org/10.1002/1521-3773(20010417)40:8<1423::AID-ANIE1423>3.0.CO;2-GDOI Listing

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