Manipulation of the coordination sphere of an Fe ion can be used to tune the balance between different catalytic pathways for oxidation (OH versus iron-based oxidant; see scheme). This reinvestigation of Fenton chemistry uses the iron complex shown as a mechanistic probe.
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| http://dx.doi.org/10.1002/1521-3773(20010302)40:5<949::AID-ANIE949>3.0.CO;2-4 | DOI Listing |
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