AI Article Synopsis
- Metal-metal bonds are not required for the formation of complexes with multiple bridging hydride ligands.
- A new tetranuclear μ-hydride complex has been created, featuring a quadruply bridging hydride that connects four isolated rhodium metal centers.
- The complex has been analyzed using spectroscopic techniques and single-crystal X-ray diffraction to understand its structure.
Article Abstract
Metal-metal bonds are not essential for multiply bridging hydride ligands. A tetranuclear μ -hydride complex [(μ -H)Rh (PNNP) (CO) ] (PNNP=3,5-bis(diphenylphosphanylmethyl)pyrazolate), in which the quadruply bridging hydrido ligand holds the four isolated metal centers together to form a tetrahedral metal array, has been prepared and characterized by spectroscopic methods and single-crystal X-ray diffraction.
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| http://dx.doi.org/10.1002/1521-3773(20010803)40:15<2865::AID-ANIE2865>3.0.CO;2-5 | DOI Listing |
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