A vertex-sharing double square pyramid of cobalt(II) ions (see picture) is present in the nonanuclear complex 1, obtained by treating cobalt acetate with 0.5 equivalents of (py )CO. The corresponding 1:1 reaction gave 2, which has a central core with a cubane structure. py=pyridine.
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State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
Among numerous heterometallic chalcogenidoantimonates, relatively a few amine-directed Ge-Sb-S compounds have been synthesized. Presented here are the solvothermal syntheses, crystal structures, and ion-exchange, optical, and photocatalytic properties of two novel amine-directed Ge-Sb-S compounds, namely, [CH3NH3]20Ge10Sb28S72·7H2O (1) and [(CH3CH2CH2)2NH2]3Ge3Sb5S15·0.5(C2H5OH) (2).
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Dalton Trans
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Inorg Chem
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